CA2192771A1 - Process for preparing a cycloolefin copolymer - Google Patents

Process for preparing a cycloolefin copolymer

Info

Publication number
CA2192771A1
CA2192771A1 CA002192771A CA2192771A CA2192771A1 CA 2192771 A1 CA2192771 A1 CA 2192771A1 CA 002192771 A CA002192771 A CA 002192771A CA 2192771 A CA2192771 A CA 2192771A CA 2192771 A1 CA2192771 A1 CA 2192771A1
Authority
CA
Canada
Prior art keywords
preparing
cycloolefin copolymer
ligand
polymerization
bridge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002192771A
Other languages
French (fr)
Other versions
CA2192771C (en
Inventor
Michael Riedel
Thomas Weller
Alexandra Jacobs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ticona GmbH
Mitsui Petrochemical Industries Ltd
Original Assignee
Hoechst AG
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Mitsui Petrochemical Industries Ltd filed Critical Hoechst AG
Publication of CA2192771A1 publication Critical patent/CA2192771A1/en
Application granted granted Critical
Publication of CA2192771C publication Critical patent/CA2192771C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

The present invention relates to a process for preparing a cycloolefin copolymer by polymerization of at least one cyclic olefin and at least one acyclic olefin in the presence of a catalyst comprising at least one metallocene compound of the formula I,
CA002192771A 1995-12-13 1996-12-12 Process for preparing a cycloolefin copolymer Expired - Lifetime CA2192771C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19546500.8 1995-12-13
DE19546500A DE19546500A1 (en) 1995-12-13 1995-12-13 Production of cyclo-olefin copolymers e.g. for pipes

Publications (2)

Publication Number Publication Date
CA2192771A1 true CA2192771A1 (en) 1997-06-14
CA2192771C CA2192771C (en) 2007-03-27

Family

ID=7779982

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002192771A Expired - Lifetime CA2192771C (en) 1995-12-13 1996-12-12 Process for preparing a cycloolefin copolymer

Country Status (8)

Country Link
US (2) US5869586A (en)
EP (1) EP0779306B1 (en)
JP (1) JPH09176223A (en)
KR (1) KR100480532B1 (en)
CN (1) CN1089771C (en)
CA (1) CA2192771C (en)
DE (2) DE19546500A1 (en)
TW (1) TW356473B (en)

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US6072014A (en) * 1997-10-17 2000-06-06 Sri International Multimodal polymer compositions prepared using multinuclear metallocene catalysts
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions

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DE19652340A1 (en) * 1996-12-17 1998-06-18 Hoechst Ag Process for the preparation of cycloolefin copolymers
US6517781B1 (en) * 1997-06-02 2003-02-11 Aurora Biosciences Corporation Low fluorescence assay platforms and related methods for drug discovery
US5892079A (en) * 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use
US6096677A (en) * 1997-10-17 2000-08-01 Sri International Supported metallocene catalysts
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US6861035B2 (en) * 1998-02-24 2005-03-01 Aurora Discovery, Inc. Multi-well platforms, caddies, lids and combinations thereof
EP0965614B1 (en) 1998-06-16 2006-03-15 Ticona GmbH Impact resistant cycloolefin-copolymer blend
US6228790B1 (en) * 1998-06-29 2001-05-08 Industrial Technology Research Institute Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer
US6455458B1 (en) 1998-07-10 2002-09-24 Exxonmobil Chemical Patents Inc. Tethered monocyclopentadienyl polymerization catalysts
EP0985677A1 (en) * 1998-09-07 2000-03-15 Industrial Technology Research Institute Dinuclear metallocene catalyst for olefin polymerization
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US6339035B1 (en) * 1999-02-22 2002-01-15 Phillips Petroleum Company Catalyst and process for polymerizing olefins
DE19929809A1 (en) 1999-06-30 2001-01-04 Ticona Gmbh Continuous process for the production of an amorphous polyolefin with a broad molar mass distribution and uniform glass temperature
DE19932384A1 (en) * 1999-07-14 2001-01-18 Mitsubishi Polyester Film Gmbh White, biaxially oriented polyester film with cycloolefin copolymer (COC), process for its production and its use
KR100416470B1 (en) * 1999-12-20 2004-01-31 삼성아토피나주식회사 Ethylene-Aromatic Vinyl Compound-Vinyl Norbonene Terpolymer
US6906147B2 (en) * 2002-03-20 2005-06-14 Cyclics Corporation Catalytic systems
US7151143B2 (en) * 2000-01-21 2006-12-19 Cyclics Corporation Blends containing macrocyclic polyester oligomer and high molecular weight polymer
US6960626B2 (en) * 2000-01-21 2005-11-01 Cyclics Corporation Intimate physical mixtures containing macrocyclic polyester oligomer and filler
US7256241B2 (en) * 2000-01-21 2007-08-14 Cyclics Corporation Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters
US20050282952A1 (en) * 2000-01-21 2005-12-22 Cyclics Corporation Graphite-polyester composites made from macrocyclic polyester oligomers
US6420047B2 (en) * 2000-01-21 2002-07-16 Cyclics Corporation Macrocyclic polyester oligomers and processes for polymerizing the same
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US6875719B2 (en) * 2000-04-27 2005-04-05 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
US20020147104A1 (en) * 2000-04-27 2002-10-10 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
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US7750109B2 (en) 2000-09-01 2010-07-06 Cyclics Corporation Use of a residual oligomer recyclate in the production of macrocyclic polyester oligomer
EP1313789B1 (en) * 2000-09-01 2006-07-19 Cyclics Corporation Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters
US7767781B2 (en) * 2000-09-01 2010-08-03 Cyclics Corporation Preparation of low-acid polyalkylene terephthalate and preparation of macrocyclic polyester oligomer therefrom
US6372848B1 (en) 2000-10-10 2002-04-16 Baxter International Inc. Blend of ethylene and α-olefin copolymers obtained using a metallocene catalyst for fabricating medical films and tubings
KR100417037B1 (en) * 2000-12-22 2004-02-05 이동호 Method for preparing cycloolefin copolymer having desirable material properties
US6696524B2 (en) 2001-02-20 2004-02-24 E. I. Du Pont De Nemours And Company Low Tg ethylene-based polymer, cycloolefin polymer blends
US6670423B2 (en) 2001-02-20 2003-12-30 E. I. Du Pont De Nemours And Company Polar ethylene-based polymer, cycloolefin polymer blends
JP2002338617A (en) * 2001-05-22 2002-11-27 Sumitomo Chem Co Ltd Catalyst component for vinyl compound polymerization, vinyl compound polymerization catalyst, production method for vinyl compound polymer, and using method for transition metal compound
US7304123B2 (en) * 2001-06-27 2007-12-04 Cyclics Corporation Processes for shaping macrocyclic oligoesters
CN1547577A (en) * 2001-06-27 2004-11-17 Isolation, formulation, and shaping of macrocyclic oligoesters
US20030077466A1 (en) * 2001-10-19 2003-04-24 Smith Sidney T. Multilayered polymer structure
JP4704682B2 (en) * 2001-12-21 2011-06-15 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Multilayer film
US20030125662A1 (en) * 2002-01-03 2003-07-03 Tuan Bui Method and apparatus for providing medical treatment therapy based on calculated demand
US7238164B2 (en) * 2002-07-19 2007-07-03 Baxter International Inc. Systems, methods and apparatuses for pumping cassette-based therapies
US6831188B1 (en) 2002-07-31 2004-12-14 Albemarle Corporation Dihydrocarbylamino metal compounds
WO2004024739A1 (en) * 2002-09-12 2004-03-25 Dow Global Technologies Inc. Preparation of metal amide complexes
JP2005539060A (en) * 2002-09-12 2005-12-22 ダウ・グローバル・テクノロジーズ・インコーポレイテッド Method for producing metal complex
KR100576971B1 (en) * 2002-09-13 2006-05-10 금호석유화학 주식회사 A method for producing dinuclear transition metal complexes as olefin polymerization catalyst
WO2004026925A1 (en) 2002-09-17 2004-04-01 Dow Global Technologies Inc. Improved process for manufacture of polymers
US7037989B2 (en) * 2003-05-27 2006-05-02 Exxonmobil Chemical Patents Inc. Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
CN1871291B (en) * 2003-09-26 2011-01-12 路博润高级材料公司 A transparent thermoplastic blend of a cycloolefin copolymer and a thermoplastic polyurethane
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EP1694771B1 (en) * 2003-12-19 2010-03-10 Cyclics Corporation Processes for dispersing an impact modifier in a macrocyclic polyester oligomer
US20050209563A1 (en) * 2004-03-19 2005-09-22 Peter Hopping Cassette-based dialysis medical fluid therapy systems, apparatuses and methods
JP4724178B2 (en) * 2005-03-18 2011-07-13 三井化学株式会社 Resin composition for solar cell container
JP4830800B2 (en) * 2006-11-09 2011-12-07 Ｊｓｒ株式会社 Manufacturing method of thin optical lens molding
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US8558964B2 (en) 2007-02-15 2013-10-15 Baxter International Inc. Dialysis system having display with electromagnetic compliance (“EMC”) seal
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US7998115B2 (en) * 2007-02-15 2011-08-16 Baxter International Inc. Dialysis system having optical flowrate detection
US8361023B2 (en) * 2007-02-15 2013-01-29 Baxter International Inc. Dialysis system with efficient battery back-up
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Publication number Priority date Publication date Assignee Title
US6072014A (en) * 1997-10-17 2000-06-06 Sri International Multimodal polymer compositions prepared using multinuclear metallocene catalysts
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
US6943226B2 (en) 1999-10-06 2005-09-13 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions

Also Published As

Publication number Publication date
KR100480532B1 (en) 2005-07-07
TW356473B (en) 1999-04-21
EP0779306B1 (en) 2003-12-03
EP0779306A2 (en) 1997-06-18
DE19546500A1 (en) 1997-06-19
EP0779306A3 (en) 1999-03-03
US5869586A (en) 1999-02-09
KR970042568A (en) 1997-07-24
CA2192771C (en) 2007-03-27
JPH09176223A (en) 1997-07-08
CN1089771C (en) 2002-08-28
CN1151995A (en) 1997-06-18
US6020444A (en) 2000-02-01
DE59610845D1 (en) 2004-01-15

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