CA2176623A1 - Production of Polyethylene Using Stereoisomeric Metallocenes - Google Patents
Production of Polyethylene Using Stereoisomeric MetallocenesInfo
- Publication number
- CA2176623A1 CA2176623A1 CA2176623A CA2176623A CA2176623A1 CA 2176623 A1 CA2176623 A1 CA 2176623A1 CA 2176623 A CA2176623 A CA 2176623A CA 2176623 A CA2176623 A CA 2176623A CA 2176623 A1 CA2176623 A1 CA 2176623A1
- Authority
- CA
- Canada
- Prior art keywords
- polyethylene
- stereoisomeric
- metallocenes
- production
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 Polyethylene Polymers 0.000 title abstract 2
- 239000004698 Polyethylene Substances 0.000 title abstract 2
- 229920000573 polyethylene Polymers 0.000 title abstract 2
- 125000001485 cycloalkadienyl group Chemical group 0.000 abstract 1
- 230000001815 facial effect Effects 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
Polyethylene having a broad molecular weight distribution, a narrow comonomer distribution and excellent processability is easily and cost effectively made using stereoisomeric mixtures of bridged metallocene catalysts containing cycloalkadienyl ligands with facial chirality.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US44227995A | 1995-05-16 | 1995-05-16 | |
US08/442,279 | 1995-05-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2176623A1 true CA2176623A1 (en) | 1996-11-17 |
CA2176623C CA2176623C (en) | 2000-07-25 |
Family
ID=23756211
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002176623A Expired - Fee Related CA2176623C (en) | 1995-05-16 | 1996-05-15 | Production of polyethylene using stereoisomeric metallocenes |
Country Status (10)
Country | Link |
---|---|
US (1) | US5852143A (en) |
EP (2) | EP1217013A3 (en) |
JP (1) | JP3071145B2 (en) |
AT (1) | ATE223929T1 (en) |
AU (1) | AU706842B2 (en) |
BR (1) | BR9602268A (en) |
CA (1) | CA2176623C (en) |
DE (1) | DE69623528T2 (en) |
ES (1) | ES2182950T3 (en) |
PT (1) | PT743324E (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6903307B1 (en) | 2004-10-04 | 2005-06-07 | Prince Lionheart, Inc. | Hygienic wipes steamer |
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US6177527B1 (en) * | 1998-09-08 | 2001-01-23 | Union Carbide Chemical & Plastics Technology Corporation | Process for the preparation of polyethylene or polypropylene |
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EP1062257A1 (en) * | 1999-01-08 | 2000-12-27 | The Board Of Trustees Of The Leland Stanford Junior University | Ethylene copolymers with narrow composition distribution and high melting temperatures, and methods of production thereof |
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DE59210001D1 (en) * | 1991-10-15 | 2005-02-17 | Basell Polyolefine Gmbh | Process for the preparation of an olefin polymer using metallocenes with specifically substituted indenyl ligands |
US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
EP0882731A3 (en) * | 1992-08-15 | 2000-05-31 | TARGOR GmbH | Bridged metallocene compounds and their use as olefin polymerization catalysts |
CA2145635A1 (en) * | 1992-09-29 | 1994-04-14 | Patrick Brant | Long chain branched polymers and a process to make long chain branched polymers |
US5317036A (en) * | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
US5420220A (en) * | 1993-03-25 | 1995-05-30 | Mobil Oil Corporation | LLDPE films |
WO1994028034A1 (en) * | 1993-05-25 | 1994-12-08 | Exxon Chemical Patents Inc. | Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof |
IT1271406B (en) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | PROCEDURE FOR THE PREPARATION OF ETHYLENE POLYMERS AND OBTAINED PRODUCTS |
ATE169936T1 (en) * | 1993-12-21 | 1998-09-15 | Union Carbide Chem Plastic | PRODUCTION OF POLYOLEFINS WITH LANG-CHAIN BRANCHING BY A GAS PHASE PROCESS |
IT1270253B (en) * | 1994-06-20 | 1997-04-29 | Spherilene Srl | ETHYLENE COPOLYMERS AND PROCEDURE FOR THE PREPARATION OF ETHYLENE POLYMERS |
DE69500979T2 (en) * | 1994-07-22 | 1998-03-05 | Mitsubishi Chem Corp | Catalyst component for alpha olefin polymerization and process for producing alpha olefin polymers using the same |
-
1996
- 1996-05-15 JP JP8143479A patent/JP3071145B2/en not_active Expired - Fee Related
- 1996-05-15 EP EP02001089A patent/EP1217013A3/en not_active Withdrawn
- 1996-05-15 PT PT96303442T patent/PT743324E/en unknown
- 1996-05-15 EP EP96303442A patent/EP0743324B1/en not_active Expired - Lifetime
- 1996-05-15 ES ES96303442T patent/ES2182950T3/en not_active Expired - Lifetime
- 1996-05-15 CA CA002176623A patent/CA2176623C/en not_active Expired - Fee Related
- 1996-05-15 DE DE69623528T patent/DE69623528T2/en not_active Expired - Fee Related
- 1996-05-15 AT AT96303442T patent/ATE223929T1/en not_active IP Right Cessation
- 1996-05-15 BR BR9602268A patent/BR9602268A/en not_active IP Right Cessation
- 1996-05-15 AU AU52284/96A patent/AU706842B2/en not_active Ceased
-
1997
- 1997-04-16 US US08/838,182 patent/US5852143A/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6903307B1 (en) | 2004-10-04 | 2005-06-07 | Prince Lionheart, Inc. | Hygienic wipes steamer |
Also Published As
Publication number | Publication date |
---|---|
DE69623528T2 (en) | 2003-03-20 |
AU5228496A (en) | 1996-11-28 |
US5852143A (en) | 1998-12-22 |
BR9602268A (en) | 1998-04-07 |
EP0743324A3 (en) | 1997-10-22 |
PT743324E (en) | 2003-01-31 |
ATE223929T1 (en) | 2002-09-15 |
EP1217013A2 (en) | 2002-06-26 |
EP1217013A3 (en) | 2004-12-22 |
CA2176623C (en) | 2000-07-25 |
AU706842B2 (en) | 1999-06-24 |
ES2182950T3 (en) | 2003-03-16 |
JPH08311121A (en) | 1996-11-26 |
DE69623528D1 (en) | 2002-10-17 |
JP3071145B2 (en) | 2000-07-31 |
EP0743324A2 (en) | 1996-11-20 |
MX9601811A (en) | 1997-07-31 |
EP0743324B1 (en) | 2002-09-11 |
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