CA2101365A1 - Color changing compositions - Google Patents

Color changing compositions

Info

Publication number
CA2101365A1
CA2101365A1 CA2101365A CA2101365A CA2101365A1 CA 2101365 A1 CA2101365 A1 CA 2101365A1 CA 2101365 A CA2101365 A CA 2101365A CA 2101365 A CA2101365 A CA 2101365A CA 2101365 A1 CA2101365 A1 CA 2101365A1
Authority
CA
Canada
Prior art keywords
coloring composition
coloring
reducing agent
undercolor
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2101365A
Other languages
French (fr)
Other versions
CA2101365C (en
Inventor
Richard E. Miller
Charlene R. Couch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Crayola LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2101365A1 publication Critical patent/CA2101365A1/en
Application granted granted Critical
Publication of CA2101365C publication Critical patent/CA2101365C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/54No clear coat specified
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/36Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44DPAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
    • B44D2/00Special techniques in artistic painting or drawing, e.g. oil painting, water painting, pastel painting, relief painting
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2451/00Type of carrier, type of coating (Multilayers)

Abstract

A multiple coloring composition system is disclosed whose coloring effect is changed upon treatment with a second coloring composition, once the second coloring composition has been deposited over the undercolor coloring composition. The multiple ink system comprises:
(a) an undercolor aqueous coloring composition comprising an undercolor dye whose coloring ability is destroyed in the presence of a pH of about 10 or greater and/or by a reducing agent; and (b) an overcolor aqueous coloring composition comprising a colorant capable of maintaining its characteristic color in the presence of a pH of about 10 or greater and/or a reducing agent, a base in an amount sufficient to yield a pH of the overcolor composition of about 10 or greater, and/or a reducing agent.
CA002101365A 1992-07-31 1993-07-27 Color changing compositions Expired - Lifetime CA2101365C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/923,308 1992-07-31
US07/923,308 US5232494A (en) 1992-07-31 1992-07-31 Color changing compositions
US08/089,503 US5326388A (en) 1992-07-31 1993-07-16 Color changing compositions
US08/089,503 1993-07-16

Publications (2)

Publication Number Publication Date
CA2101365A1 true CA2101365A1 (en) 1994-02-01
CA2101365C CA2101365C (en) 1998-12-15

Family

ID=26780644

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002101365A Expired - Lifetime CA2101365C (en) 1992-07-31 1993-07-27 Color changing compositions

Country Status (7)

Country Link
US (2) US5232494A (en)
EP (1) EP0584571B1 (en)
AU (1) AU669373B2 (en)
CA (1) CA2101365C (en)
DE (1) DE69322711T2 (en)
ES (1) ES2128370T3 (en)
MX (1) MX9304604A (en)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5503665A (en) * 1992-07-31 1996-04-02 Binney & Smith Inc. Latent image compositions
US5492558A (en) * 1992-07-31 1996-02-20 Binney & Smith Inc. Color changing compositions for highlighters
US5498282A (en) * 1992-07-31 1996-03-12 Binney & Smith Inc. Color changing pan paint compositions
US5232494A (en) * 1992-07-31 1993-08-03 Binney & Smith Inc. Color changing compositions
US5489331A (en) * 1992-07-31 1996-02-06 Binney & Smith Inc. Color changing compositions using acids
US5478382A (en) * 1992-07-31 1995-12-26 Binney & Smith Inc. Color changing compositions for use on non-porous surfaces
US5352282A (en) * 1992-07-31 1994-10-04 Binney & Smith, Inc. Color changing compositions
US5486228A (en) 1992-07-31 1996-01-23 Binney & Smith Inc. Washable color changing compositions
MX9206283A (en) * 1992-09-18 1994-03-31 Guillette Company SET OR SET OF INKS OF DIFFERENT COLORS AND A SET OF WRITING INSTRUMENTS
AU727719B2 (en) * 1992-09-18 2000-12-21 Berol Corporation Assembly or set of different color inks and an assembly of writing instruments
US5569637A (en) * 1993-12-08 1996-10-29 Cullman Ventures, Inc. Featuring information on a record using color
US5548010A (en) * 1993-12-29 1996-08-20 Franer Victor R Color dissipatable paint
US5474578A (en) * 1994-10-03 1995-12-12 Clairol, Inc. Erasable hair dyeing process
US5464470A (en) * 1995-02-10 1995-11-07 Binney & Smith Inc. Color-changing marking composition system
US5460647A (en) * 1995-02-10 1995-10-24 Binney & Smith Inc. Color-changing marking composition system
EP0761781A4 (en) * 1995-02-20 1998-11-18 Kao Corp Water-base pigment ink
US5649999A (en) * 1996-02-22 1997-07-22 The Gillette Company Ink eradicator system
US5814579A (en) * 1996-08-06 1998-09-29 The Standard Register Company Multicolor printing system
US5916357A (en) 1997-03-25 1999-06-29 The Gillette Company Eradicable inks
DE19722546B4 (en) * 1997-05-30 2004-08-26 J. S. Staedtler Gmbh & Co. Kg Ink for changing color applications
US5916949A (en) 1997-08-18 1999-06-29 Mattel, Inc. Moldable compositions and method of making the same
US6004057A (en) * 1997-11-24 1999-12-21 Fulop; Jacqueline I. Marking and eradicating instrument and method of use of same
US6124377A (en) * 1998-07-01 2000-09-26 Binney & Smith Inc. Marking system
AU5899599A (en) * 1998-09-04 2000-03-27 A.J. Daw Printing Ink Co., Inc. Composition and method of use for bleachable, transfer resistant pigmented ink
US6261631B1 (en) 1998-12-22 2001-07-17 Tnemec Company, Inc. Method for controlling wet film thickness of clear coatings by means of color-dissipating dye
US6149721A (en) * 1999-02-03 2000-11-21 The Gillette Company Solvent-based pen inks
FR2818655B1 (en) * 2000-12-22 2004-05-14 Conte COLORED LIQUID COMPOSITION FOR HIGHLIGHTER
CA2441280C (en) 2001-03-19 2013-04-30 L'avant Garde Inc. Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes
WO2004053004A1 (en) * 2002-12-06 2004-06-24 Polaroid Corporation Water-immersion indicator indicia and articles bearing such indicia
US6905539B2 (en) * 2003-07-15 2005-06-14 Sanford L.P. Black eradicable ink, methods of eradication of the same, eradicable ink kit, and eradicated ink complex
US20050192379A1 (en) * 2003-07-15 2005-09-01 Kwan Wing S.V. Eradicable composition and kit
US7442725B2 (en) * 2003-10-02 2008-10-28 Sanford, L.P. Color changing correction fluid
US7704308B2 (en) * 2003-10-07 2010-04-27 Sanford, L.P. Method of highlighting with a reversible highlighting mixture, highlighting kit, and highlighted complex
US7488380B2 (en) * 2003-10-07 2009-02-10 Sanford, L.P. Highlighting marking compositions, highlighting kits, and highlighted complexes
US7083665B1 (en) * 2003-10-07 2006-08-01 Sanford, L.P. Highlightable marking composition, method of highlighting the same, highlightable marking composition kit, and highlighted marking composition complex
US20050143505A1 (en) * 2003-12-05 2005-06-30 Rosekelly George S. Paint with color change additive and method of application and painted substrate
US7229487B2 (en) * 2004-01-14 2007-06-12 Sanford, L.P. Writing instruments with eradicable inks and eradicating fluids
US7521112B2 (en) * 2004-06-29 2009-04-21 Crayola Llc Coated art material system
US7163575B2 (en) * 2004-07-15 2007-01-16 Sanford, L.P. Water-based, resin-free and solvent-free eradicable ball-pen inks
AU2005248941A1 (en) * 2004-08-19 2006-03-09 Sanford, L.P. Decoder system
BRPI0615162A2 (en) * 2005-08-04 2016-09-13 Sanford Lp correction fluid, correction fluid applicator, capillary action marker, and method for producing a correction fluid
FR2909680B1 (en) * 2006-12-11 2010-12-10 Bic Soc CORRECTIVE FLUID WITH DRYING INDICATOR
US7939053B2 (en) * 2007-04-12 2011-05-10 L'oreal S.A. Method of making up nails
US20090215621A1 (en) * 2008-02-27 2009-08-27 Elmer's Products, Inc. Coloring system with encapsulated dyes
CN105713968A (en) * 2009-03-19 2016-06-29 株式会社钟化 Method for detecting nucleic acid, and device, kit
EP2581422A1 (en) * 2011-10-11 2013-04-17 Sicpa Holding Sa Ink coatings for security documents to prevent forgery by means of heat sensitive erasable ink
US8822374B2 (en) 2012-01-06 2014-09-02 Nocopi Technologies, Inc. Color-changing marking implement and substrate
US9109126B2 (en) 2013-07-22 2015-08-18 Sanford, L.P. Ink compositions comprising colorant particles containing polymeric particles
GB2520633B (en) 2013-11-25 2021-06-02 Crayola Llc Marking system
US11007813B2 (en) 2018-04-25 2021-05-18 Crayola Llc Integrated highlighting and shading marker system
US11746235B2 (en) 2019-06-21 2023-09-05 Crayola Llc Two part silicone moldable eraser
US11680181B1 (en) 2021-09-29 2023-06-20 W. Thomas Forlander Industrial coating with color-change responsivity to acid and base contact

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE551775C (en) * 1927-05-24 1932-06-04 I G Farbenindustrie Akt Ges Process for producing two-color or multicolor effects on cellulose ethers, esters or their conversion products colored with nitroanthraquinones or substitution products thereof
US2305098A (en) * 1940-07-15 1942-12-15 Columbian Bank Note Company Protective paper and ink therefor
US2589306A (en) * 1948-03-30 1952-03-18 Helen J Steiner Bleachable transfer ink
US2555474A (en) * 1948-06-04 1951-06-05 Vries John De Safety ink
US2559608A (en) * 1948-11-26 1951-07-10 Joseph R Ehrlich Multicolor carbon paper
US3400003A (en) * 1963-04-02 1968-09-03 American Bank Note Co Safety inks and documents
US3672842A (en) * 1969-06-02 1972-06-27 Walter Florin Writing instrument and indicator method
US3705045A (en) * 1970-11-12 1972-12-05 American Cyanamid Co Ink marking compositions
US3876496A (en) * 1973-05-14 1975-04-08 Ernesto B Lozano Method and means for protecting documents
ZA745027B (en) * 1973-08-16 1975-08-27 Hoechst Ag Process for obtaining irregular shadow dyeings on polyester fibres and mixtures thereof
ZA742756B (en) * 1973-08-25 1975-09-24 Hoechst Ag Animal identification tag process and device for the irregular dyeing of textiles
US3886083A (en) * 1974-05-09 1975-05-27 American Bank Note Co Safety inks and documents
JPS51137506A (en) * 1975-05-22 1976-11-27 Konishiroku Photo Ind Composition of ink for ink jet recording
DE2724820C3 (en) * 1977-06-02 1979-11-15 Schwan Stabilo Schwanhaeusser Process and equipment for producing paint smears on a surface
US4139965A (en) * 1977-09-12 1979-02-20 Mattel, Inc. Device using coated paper and chemical reactive marker
JPS5456234A (en) * 1977-10-11 1979-05-07 Toyota Motor Corp Dynamo-blower for internal engine driving
JPS54131428A (en) * 1978-04-03 1979-10-12 Adger Kogyo Co Ltd Ink
DE2834459C2 (en) * 1978-08-05 1983-07-07 Fa. J.S. Staedtler, 8500 Nürnberg Use of reducible ink for labeling or coating of plastic foils and ink for this
US4213717A (en) * 1978-11-13 1980-07-22 Burroughs Corporation Ball point pen, ink and its eradicator system
US4252845A (en) * 1978-11-30 1981-02-24 Zipatone, Inc. Graphic arts ink and eradicator combination
DE2927006A1 (en) * 1979-07-04 1981-01-08 Kreuzer Werk Gmbh Water-soluble removable stamping ink compsn. - contg. reducible dye, opt. non-reducible dye and pref. solubiliser, stabiliser and reduction accelerator
DE2927005A1 (en) * 1979-07-04 1981-01-08 Kreuzer Werk Gmbh Removable print-forming stamping compsn. - contg. flexible thermoplastics, pref. soft PVC, reducible water-soluble dye and opt. cellulose fibres
JPS5657862A (en) * 1979-10-17 1981-05-20 Seiko Epson Corp Ink for ink-jet recording
JPS56118471A (en) * 1980-02-25 1981-09-17 Konishiroku Photo Ind Co Ltd Ink composition for ink jet recording
EP0044690B1 (en) * 1980-07-19 1985-05-29 Hubdean Limited Anti-graffiti facing of walls or similar surfaces
US4557618A (en) * 1981-12-25 1985-12-10 Pentel Kabushiki Kaisha Ink and eraser of the ink
US4490177A (en) * 1982-02-02 1984-12-25 Sakura Color Products Corp. Dual color ink composition
DE3207217A1 (en) * 1982-02-27 1983-09-15 Geha-Werke Gmbh, 3000 Hannover Marking fluid
US4505749A (en) * 1983-06-24 1985-03-19 Canon Kabushiki Kaisha Method of forming color images
US4681471A (en) * 1983-08-03 1987-07-21 All-Mark Corporation, Inc. Kit comprising multicolored fluid dispenser markers together with eradicating fluid dispenser, stamps and stamp pad
JPS61113672A (en) * 1984-11-08 1986-05-31 Canon Inc Recording liquid
JPS62116676A (en) * 1985-11-18 1987-05-28 Canon Inc Recording fluid
US4708817A (en) * 1986-08-08 1987-11-24 Dudnick Steven L Creative art medium for forming artistic expressions having a latent luminescent image pattern
GB8704680D0 (en) * 1987-02-27 1987-04-01 Minnesota Mining & Mfg Indicator elements for autoclaves
US4756758A (en) * 1987-04-24 1988-07-12 Videojet Systems International, Inc. Thermochromic jet ink
DE3842774C1 (en) * 1988-12-19 1990-03-15 Pelikan Ag, 3000 Hannover, De
US5232494A (en) * 1992-07-31 1993-08-03 Binney & Smith Inc. Color changing compositions

Also Published As

Publication number Publication date
ES2128370T3 (en) 1999-05-16
CA2101365C (en) 1998-12-15
AU4437293A (en) 1994-02-03
MX9304604A (en) 1994-05-31
EP0584571A2 (en) 1994-03-02
EP0584571A3 (en) 1995-03-29
EP0584571B1 (en) 1998-12-23
DE69322711D1 (en) 1999-02-04
US5326388A (en) 1994-07-05
DE69322711T2 (en) 1999-06-10
US5232494A (en) 1993-08-03
AU669373B2 (en) 1996-06-06

Similar Documents

Publication Publication Date Title
CA2101365A1 (en) Color changing compositions
CA2152547A1 (en) Washable Overwriters
CA2152543A1 (en) Color Changing Pan Paint Compositions
AU4009593A (en) Reactive dye composition and dyeing or printing process using the same
CA2042487A1 (en) Hair colorants
AU694699B2 (en) Pyrazolo-(1,5-a)-pyrimidine derivatives, their preparation and hair dyes containing these
CA2027608A1 (en) Hair revitalizing agent
AU3232897A (en) Colored pigment and aqueous compositions containing same
EP0587908A4 (en) Novel cosmetic
EP0621319A3 (en) Pigment composition, printing ink and coating composition.
EP0533937A4 (en) Acidic hair dye composition
ZA936552B (en) Color cosmetic composition.
MX9805303A (en) Hair coloring compositions.
EP0589656A3 (en) Method of coloring hair with water soluble acid dyes.
CA2211446A1 (en) Colored jelly-type substance, method of preparation, and composition containing same
AU4542296A (en) Antimicrobic composition and its use
CA2235733A1 (en) Dye migration
AU695060B2 (en) Coloring paint composition
AU7766991A (en) Printing inks, and methods of printing
CA2082542A1 (en) Oxidative hair coloring compositions and process for dyeing human keratinous fibers
AU4897593A (en) Dyestuff composition for the gradual dyeing of hair by atmospheric oxidation and process using the same
AU4947196A (en) Hair dye composition containing a product of grinding plants or parts of plants of the species impatiens balsamina, and its application
CA2108840A1 (en) Compositions and methods for temporarily coloring hair using chemically synthesized or biosynthetic water-soluble melanin
AU5150596A (en) Photochromic spiropyrans, and compositions and articles cont aining same
CA2136459A1 (en) Process and kit for dyeing hair

Legal Events

Date Code Title Description
EEER Examination request