CA2101365A1 - Color changing compositions - Google Patents
Color changing compositionsInfo
- Publication number
- CA2101365A1 CA2101365A1 CA2101365A CA2101365A CA2101365A1 CA 2101365 A1 CA2101365 A1 CA 2101365A1 CA 2101365 A CA2101365 A CA 2101365A CA 2101365 A CA2101365 A CA 2101365A CA 2101365 A1 CA2101365 A1 CA 2101365A1
- Authority
- CA
- Canada
- Prior art keywords
- coloring composition
- coloring
- reducing agent
- undercolor
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
- B44D2/00—Special techniques in artistic painting or drawing, e.g. oil painting, water painting, pastel painting, relief painting
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2451/00—Type of carrier, type of coating (Multilayers)
Abstract
A multiple coloring composition system is disclosed whose coloring effect is changed upon treatment with a second coloring composition, once the second coloring composition has been deposited over the undercolor coloring composition. The multiple ink system comprises:
(a) an undercolor aqueous coloring composition comprising an undercolor dye whose coloring ability is destroyed in the presence of a pH of about 10 or greater and/or by a reducing agent; and (b) an overcolor aqueous coloring composition comprising a colorant capable of maintaining its characteristic color in the presence of a pH of about 10 or greater and/or a reducing agent, a base in an amount sufficient to yield a pH of the overcolor composition of about 10 or greater, and/or a reducing agent.
(a) an undercolor aqueous coloring composition comprising an undercolor dye whose coloring ability is destroyed in the presence of a pH of about 10 or greater and/or by a reducing agent; and (b) an overcolor aqueous coloring composition comprising a colorant capable of maintaining its characteristic color in the presence of a pH of about 10 or greater and/or a reducing agent, a base in an amount sufficient to yield a pH of the overcolor composition of about 10 or greater, and/or a reducing agent.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/923,308 | 1992-07-31 | ||
US07/923,308 US5232494A (en) | 1992-07-31 | 1992-07-31 | Color changing compositions |
US08/089,503 US5326388A (en) | 1992-07-31 | 1993-07-16 | Color changing compositions |
US08/089,503 | 1993-07-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2101365A1 true CA2101365A1 (en) | 1994-02-01 |
CA2101365C CA2101365C (en) | 1998-12-15 |
Family
ID=26780644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002101365A Expired - Lifetime CA2101365C (en) | 1992-07-31 | 1993-07-27 | Color changing compositions |
Country Status (7)
Country | Link |
---|---|
US (2) | US5232494A (en) |
EP (1) | EP0584571B1 (en) |
AU (1) | AU669373B2 (en) |
CA (1) | CA2101365C (en) |
DE (1) | DE69322711T2 (en) |
ES (1) | ES2128370T3 (en) |
MX (1) | MX9304604A (en) |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5503665A (en) * | 1992-07-31 | 1996-04-02 | Binney & Smith Inc. | Latent image compositions |
US5492558A (en) * | 1992-07-31 | 1996-02-20 | Binney & Smith Inc. | Color changing compositions for highlighters |
US5498282A (en) * | 1992-07-31 | 1996-03-12 | Binney & Smith Inc. | Color changing pan paint compositions |
US5232494A (en) * | 1992-07-31 | 1993-08-03 | Binney & Smith Inc. | Color changing compositions |
US5489331A (en) * | 1992-07-31 | 1996-02-06 | Binney & Smith Inc. | Color changing compositions using acids |
US5478382A (en) * | 1992-07-31 | 1995-12-26 | Binney & Smith Inc. | Color changing compositions for use on non-porous surfaces |
US5352282A (en) * | 1992-07-31 | 1994-10-04 | Binney & Smith, Inc. | Color changing compositions |
US5486228A (en) | 1992-07-31 | 1996-01-23 | Binney & Smith Inc. | Washable color changing compositions |
MX9206283A (en) * | 1992-09-18 | 1994-03-31 | Guillette Company | SET OR SET OF INKS OF DIFFERENT COLORS AND A SET OF WRITING INSTRUMENTS |
AU727719B2 (en) * | 1992-09-18 | 2000-12-21 | Berol Corporation | Assembly or set of different color inks and an assembly of writing instruments |
US5569637A (en) * | 1993-12-08 | 1996-10-29 | Cullman Ventures, Inc. | Featuring information on a record using color |
US5548010A (en) * | 1993-12-29 | 1996-08-20 | Franer Victor R | Color dissipatable paint |
US5474578A (en) * | 1994-10-03 | 1995-12-12 | Clairol, Inc. | Erasable hair dyeing process |
US5464470A (en) * | 1995-02-10 | 1995-11-07 | Binney & Smith Inc. | Color-changing marking composition system |
US5460647A (en) * | 1995-02-10 | 1995-10-24 | Binney & Smith Inc. | Color-changing marking composition system |
EP0761781A4 (en) * | 1995-02-20 | 1998-11-18 | Kao Corp | Water-base pigment ink |
US5649999A (en) * | 1996-02-22 | 1997-07-22 | The Gillette Company | Ink eradicator system |
US5814579A (en) * | 1996-08-06 | 1998-09-29 | The Standard Register Company | Multicolor printing system |
US5916357A (en) | 1997-03-25 | 1999-06-29 | The Gillette Company | Eradicable inks |
DE19722546B4 (en) * | 1997-05-30 | 2004-08-26 | J. S. Staedtler Gmbh & Co. Kg | Ink for changing color applications |
US5916949A (en) | 1997-08-18 | 1999-06-29 | Mattel, Inc. | Moldable compositions and method of making the same |
US6004057A (en) * | 1997-11-24 | 1999-12-21 | Fulop; Jacqueline I. | Marking and eradicating instrument and method of use of same |
US6124377A (en) * | 1998-07-01 | 2000-09-26 | Binney & Smith Inc. | Marking system |
AU5899599A (en) * | 1998-09-04 | 2000-03-27 | A.J. Daw Printing Ink Co., Inc. | Composition and method of use for bleachable, transfer resistant pigmented ink |
US6261631B1 (en) | 1998-12-22 | 2001-07-17 | Tnemec Company, Inc. | Method for controlling wet film thickness of clear coatings by means of color-dissipating dye |
US6149721A (en) * | 1999-02-03 | 2000-11-21 | The Gillette Company | Solvent-based pen inks |
FR2818655B1 (en) * | 2000-12-22 | 2004-05-14 | Conte | COLORED LIQUID COMPOSITION FOR HIGHLIGHTER |
CA2441280C (en) | 2001-03-19 | 2013-04-30 | L'avant Garde Inc. | Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes |
WO2004053004A1 (en) * | 2002-12-06 | 2004-06-24 | Polaroid Corporation | Water-immersion indicator indicia and articles bearing such indicia |
US6905539B2 (en) * | 2003-07-15 | 2005-06-14 | Sanford L.P. | Black eradicable ink, methods of eradication of the same, eradicable ink kit, and eradicated ink complex |
US20050192379A1 (en) * | 2003-07-15 | 2005-09-01 | Kwan Wing S.V. | Eradicable composition and kit |
US7442725B2 (en) * | 2003-10-02 | 2008-10-28 | Sanford, L.P. | Color changing correction fluid |
US7704308B2 (en) * | 2003-10-07 | 2010-04-27 | Sanford, L.P. | Method of highlighting with a reversible highlighting mixture, highlighting kit, and highlighted complex |
US7488380B2 (en) * | 2003-10-07 | 2009-02-10 | Sanford, L.P. | Highlighting marking compositions, highlighting kits, and highlighted complexes |
US7083665B1 (en) * | 2003-10-07 | 2006-08-01 | Sanford, L.P. | Highlightable marking composition, method of highlighting the same, highlightable marking composition kit, and highlighted marking composition complex |
US20050143505A1 (en) * | 2003-12-05 | 2005-06-30 | Rosekelly George S. | Paint with color change additive and method of application and painted substrate |
US7229487B2 (en) * | 2004-01-14 | 2007-06-12 | Sanford, L.P. | Writing instruments with eradicable inks and eradicating fluids |
US7521112B2 (en) * | 2004-06-29 | 2009-04-21 | Crayola Llc | Coated art material system |
US7163575B2 (en) * | 2004-07-15 | 2007-01-16 | Sanford, L.P. | Water-based, resin-free and solvent-free eradicable ball-pen inks |
AU2005248941A1 (en) * | 2004-08-19 | 2006-03-09 | Sanford, L.P. | Decoder system |
BRPI0615162A2 (en) * | 2005-08-04 | 2016-09-13 | Sanford Lp | correction fluid, correction fluid applicator, capillary action marker, and method for producing a correction fluid |
FR2909680B1 (en) * | 2006-12-11 | 2010-12-10 | Bic Soc | CORRECTIVE FLUID WITH DRYING INDICATOR |
US7939053B2 (en) * | 2007-04-12 | 2011-05-10 | L'oreal S.A. | Method of making up nails |
US20090215621A1 (en) * | 2008-02-27 | 2009-08-27 | Elmer's Products, Inc. | Coloring system with encapsulated dyes |
CN105713968A (en) * | 2009-03-19 | 2016-06-29 | 株式会社钟化 | Method for detecting nucleic acid, and device, kit |
EP2581422A1 (en) * | 2011-10-11 | 2013-04-17 | Sicpa Holding Sa | Ink coatings for security documents to prevent forgery by means of heat sensitive erasable ink |
US8822374B2 (en) | 2012-01-06 | 2014-09-02 | Nocopi Technologies, Inc. | Color-changing marking implement and substrate |
US9109126B2 (en) | 2013-07-22 | 2015-08-18 | Sanford, L.P. | Ink compositions comprising colorant particles containing polymeric particles |
GB2520633B (en) | 2013-11-25 | 2021-06-02 | Crayola Llc | Marking system |
US11007813B2 (en) | 2018-04-25 | 2021-05-18 | Crayola Llc | Integrated highlighting and shading marker system |
US11746235B2 (en) | 2019-06-21 | 2023-09-05 | Crayola Llc | Two part silicone moldable eraser |
US11680181B1 (en) | 2021-09-29 | 2023-06-20 | W. Thomas Forlander | Industrial coating with color-change responsivity to acid and base contact |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE551775C (en) * | 1927-05-24 | 1932-06-04 | I G Farbenindustrie Akt Ges | Process for producing two-color or multicolor effects on cellulose ethers, esters or their conversion products colored with nitroanthraquinones or substitution products thereof |
US2305098A (en) * | 1940-07-15 | 1942-12-15 | Columbian Bank Note Company | Protective paper and ink therefor |
US2589306A (en) * | 1948-03-30 | 1952-03-18 | Helen J Steiner | Bleachable transfer ink |
US2555474A (en) * | 1948-06-04 | 1951-06-05 | Vries John De | Safety ink |
US2559608A (en) * | 1948-11-26 | 1951-07-10 | Joseph R Ehrlich | Multicolor carbon paper |
US3400003A (en) * | 1963-04-02 | 1968-09-03 | American Bank Note Co | Safety inks and documents |
US3672842A (en) * | 1969-06-02 | 1972-06-27 | Walter Florin | Writing instrument and indicator method |
US3705045A (en) * | 1970-11-12 | 1972-12-05 | American Cyanamid Co | Ink marking compositions |
US3876496A (en) * | 1973-05-14 | 1975-04-08 | Ernesto B Lozano | Method and means for protecting documents |
ZA745027B (en) * | 1973-08-16 | 1975-08-27 | Hoechst Ag | Process for obtaining irregular shadow dyeings on polyester fibres and mixtures thereof |
ZA742756B (en) * | 1973-08-25 | 1975-09-24 | Hoechst Ag | Animal identification tag process and device for the irregular dyeing of textiles |
US3886083A (en) * | 1974-05-09 | 1975-05-27 | American Bank Note Co | Safety inks and documents |
JPS51137506A (en) * | 1975-05-22 | 1976-11-27 | Konishiroku Photo Ind | Composition of ink for ink jet recording |
DE2724820C3 (en) * | 1977-06-02 | 1979-11-15 | Schwan Stabilo Schwanhaeusser | Process and equipment for producing paint smears on a surface |
US4139965A (en) * | 1977-09-12 | 1979-02-20 | Mattel, Inc. | Device using coated paper and chemical reactive marker |
JPS5456234A (en) * | 1977-10-11 | 1979-05-07 | Toyota Motor Corp | Dynamo-blower for internal engine driving |
JPS54131428A (en) * | 1978-04-03 | 1979-10-12 | Adger Kogyo Co Ltd | Ink |
DE2834459C2 (en) * | 1978-08-05 | 1983-07-07 | Fa. J.S. Staedtler, 8500 Nürnberg | Use of reducible ink for labeling or coating of plastic foils and ink for this |
US4213717A (en) * | 1978-11-13 | 1980-07-22 | Burroughs Corporation | Ball point pen, ink and its eradicator system |
US4252845A (en) * | 1978-11-30 | 1981-02-24 | Zipatone, Inc. | Graphic arts ink and eradicator combination |
DE2927006A1 (en) * | 1979-07-04 | 1981-01-08 | Kreuzer Werk Gmbh | Water-soluble removable stamping ink compsn. - contg. reducible dye, opt. non-reducible dye and pref. solubiliser, stabiliser and reduction accelerator |
DE2927005A1 (en) * | 1979-07-04 | 1981-01-08 | Kreuzer Werk Gmbh | Removable print-forming stamping compsn. - contg. flexible thermoplastics, pref. soft PVC, reducible water-soluble dye and opt. cellulose fibres |
JPS5657862A (en) * | 1979-10-17 | 1981-05-20 | Seiko Epson Corp | Ink for ink-jet recording |
JPS56118471A (en) * | 1980-02-25 | 1981-09-17 | Konishiroku Photo Ind Co Ltd | Ink composition for ink jet recording |
EP0044690B1 (en) * | 1980-07-19 | 1985-05-29 | Hubdean Limited | Anti-graffiti facing of walls or similar surfaces |
US4557618A (en) * | 1981-12-25 | 1985-12-10 | Pentel Kabushiki Kaisha | Ink and eraser of the ink |
US4490177A (en) * | 1982-02-02 | 1984-12-25 | Sakura Color Products Corp. | Dual color ink composition |
DE3207217A1 (en) * | 1982-02-27 | 1983-09-15 | Geha-Werke Gmbh, 3000 Hannover | Marking fluid |
US4505749A (en) * | 1983-06-24 | 1985-03-19 | Canon Kabushiki Kaisha | Method of forming color images |
US4681471A (en) * | 1983-08-03 | 1987-07-21 | All-Mark Corporation, Inc. | Kit comprising multicolored fluid dispenser markers together with eradicating fluid dispenser, stamps and stamp pad |
JPS61113672A (en) * | 1984-11-08 | 1986-05-31 | Canon Inc | Recording liquid |
JPS62116676A (en) * | 1985-11-18 | 1987-05-28 | Canon Inc | Recording fluid |
US4708817A (en) * | 1986-08-08 | 1987-11-24 | Dudnick Steven L | Creative art medium for forming artistic expressions having a latent luminescent image pattern |
GB8704680D0 (en) * | 1987-02-27 | 1987-04-01 | Minnesota Mining & Mfg | Indicator elements for autoclaves |
US4756758A (en) * | 1987-04-24 | 1988-07-12 | Videojet Systems International, Inc. | Thermochromic jet ink |
DE3842774C1 (en) * | 1988-12-19 | 1990-03-15 | Pelikan Ag, 3000 Hannover, De | |
US5232494A (en) * | 1992-07-31 | 1993-08-03 | Binney & Smith Inc. | Color changing compositions |
-
1992
- 1992-07-31 US US07/923,308 patent/US5232494A/en not_active Expired - Lifetime
-
1993
- 1993-07-16 US US08/089,503 patent/US5326388A/en not_active Expired - Lifetime
- 1993-07-27 CA CA002101365A patent/CA2101365C/en not_active Expired - Lifetime
- 1993-07-29 ES ES93112138T patent/ES2128370T3/en not_active Expired - Lifetime
- 1993-07-29 DE DE69322711T patent/DE69322711T2/en not_active Expired - Lifetime
- 1993-07-29 EP EP93112138A patent/EP0584571B1/en not_active Expired - Lifetime
- 1993-07-30 AU AU44372/93A patent/AU669373B2/en not_active Expired
- 1993-07-30 MX MX9304604A patent/MX9304604A/en unknown
Also Published As
Publication number | Publication date |
---|---|
ES2128370T3 (en) | 1999-05-16 |
CA2101365C (en) | 1998-12-15 |
AU4437293A (en) | 1994-02-03 |
MX9304604A (en) | 1994-05-31 |
EP0584571A2 (en) | 1994-03-02 |
EP0584571A3 (en) | 1995-03-29 |
EP0584571B1 (en) | 1998-12-23 |
DE69322711D1 (en) | 1999-02-04 |
US5326388A (en) | 1994-07-05 |
DE69322711T2 (en) | 1999-06-10 |
US5232494A (en) | 1993-08-03 |
AU669373B2 (en) | 1996-06-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |