CA2095930C - Machine for recycling plastic containers, in particular bottles - Google Patents

Machine for recycling plastic containers, in particular bottles Download PDF

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Publication number
CA2095930C
CA2095930C CA 2095930 CA2095930A CA2095930C CA 2095930 C CA2095930 C CA 2095930C CA 2095930 CA2095930 CA 2095930 CA 2095930 A CA2095930 A CA 2095930A CA 2095930 C CA2095930 C CA 2095930C
Authority
CA
Canada
Prior art keywords
machine
containers
rotary body
recycled
outlet opening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA 2095930
Other languages
French (fr)
Other versions
CA2095930A1 (en
Inventor
Dario Previero
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Previero N SRL
Original Assignee
Previero N SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11191500&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2095930(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Previero N SRL filed Critical Previero N SRL
Publication of CA2095930A1 publication Critical patent/CA2095930A1/en
Application granted granted Critical
Publication of CA2095930C publication Critical patent/CA2095930C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B1/00Conditioning for facilitating separation by altering physical properties of the matter to be treated
    • B03B1/04Conditioning for facilitating separation by altering physical properties of the matter to be treated by additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • B03B9/06General arrangement of separating plant, e.g. flow sheets specially adapted for refuse
    • B03B9/061General arrangement of separating plant, e.g. flow sheets specially adapted for refuse the refuse being industrial
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/041Cleaning travelling work
    • B08B3/042Cleaning travelling work the loose articles or bulk material travelling gradually through a drum or other container, e.g. by helix or gravity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/08Cleaning containers, e.g. tanks
    • B08B9/083Removing scrap from containers, e.g. removing labels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B2101/00Type of solid waste
    • B09B2101/02Gases or liquids enclosed in discarded articles, e.g. aerosol cans or cooling systems of refrigerators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • B29B2017/0203Separating plastics from plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • B29B2017/0213Specific separating techniques
    • B29B2017/0286Cleaning means used for separation
    • B29B2017/0289Washing the materials in liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2711/00Use of natural products or their composites, not provided for in groups B29K2601/00 - B29K2709/00, for preformed parts, e.g. for inserts
    • B29K2711/12Paper, e.g. cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/712Containers; Packaging elements or accessories, Packages
    • B29L2031/7158Bottles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/744Labels, badges, e.g. marker sleeves
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S209/00Classifying, separating, and assorting solids
    • Y10S209/93Municipal solid waste sorting

Abstract

The machine comprises a hollow rotary body of large dimensions which may be loaded with the containers to be recycled, means for supplying and spraying washing fluid at a predetermined temperature to the rotary body for the mutual separation and washing of the containers and the initial separation of labels and bases, and mechanical impact means housed in the rotary body and actuated by the rotation of this body so as to exert on the containers a mechanical action suitable for the mutual separation of the containers themselves, the separation of the stoppers and the completion of the washing and label and base separation operation. The rotary body may have an inlet opening and an outlet opening for the containers to be recycled or a single inlet and outlet opening so as to form a machine operating continuously or discontinuously respectively.

Description

Machine for Recyclincx Plastic Containers, in particular Bottles The present invention relates to a machine for recycling plastic containers, in particular bottles.
The recycling of plastic bottles, and in general of all containers made from this material, requires the solution of various problems linked in particular to the dimensions and shape of these bottles, their supply in bulk form and the need to subject them not only to washing but also to separate out contaminant bodies such as labels, stoppers and bases.
It also has to be borne in m~.nd that the bottles are not always made from the same plastic material, since PVC is used in some cases and PET or other materials in other cases, which raises problems as regards t?~eir separation in terms of the material from which they are made.
At present there are very few machines able to wash and mutually separate bottles, or containers in . general, supplied in bulk or to remove the contaminant bodies accompanying them and very few machines enabling identification of the bottles in terms of the plastic material from which they are made.
Those machines which do exist are structurally and operationally complex and somewhat inadequate from the point of view of efficiency and production capacity as they are able to process only a limited number oz bottles at a time.
AT-B-389 488 discloses a cleaning machine provided with a rotary drum and spraying means fc>r supplying washing fluid into the drum.
An object of the invention is t.o provide a nuachine for the recycling of_ plastic bottles anc~ containers in ~5 general which :is structurally simple anc~ able to wash the bottles or other containers and to separate them from one another and from contaminant bodies such as labels, stoppers and bases efficiently and with. a high production output.
a further object of the invention is to provide a machine of the type described above which is also able to identify the bottles (oz- containers in general) as a function of the plastic material from which they are made.
In accordance with the invention these objects are achieved with a machine essentially r:haracterized in that it comprises a hollow rotary body of large dimensions which may be loaded with the containers to be recycled, means for supplying washing fluid at a predetermined temperature to the rotary body for the mutual separation and washing of the containers and the initial separation of labels and bases and mechanical impact means housed in the rotary body and actuated by the rotation of this body so as to exert on the containers a mechanical action suitable for the mutual separation of the containers themselves, the separation of the stoppers and the completion of the washing and label and dreg removal operation.
It has been possible to verify that the combined action of the washing fluid, far instance hot water, superheated water or steam with or. without chemical additives, preferably sprayed on the containers in order to increase the mechanical action, and the mechanical impact means, for instance mechanical blades rigid with the rotary body, moving weights connected to a fixed support housed in the rotary body or to this rotary body but oscillating with respect thereto, floating spheres or like: means, provides optimum results as regards the mutual separation of the containers, their washing and the separation of the labels, bases, stoppers and any S other contaminant bodies.
More precisely, the containers supplied in bulk are separated by the combined hydraulic and mechanical action and are washed internally and externally thereby eliminating any trace of dirt. The label and base adhesive is dissolved by the washing fluid, especially when at high temperature, and if the labels are of paper they are reduced to pulp for the same reason. If the labels are of then:"o-extensible plastic, however, the heat imparted causes them to expand and therefore become detached from the container. The mechanical action facilitates and completes the separation of labels and bases and promotes the separation of the stoppers. If the containers are of different plastic materials, for instance PVC ar_d PET, the fluid supplied, especially if appropriate additives are added, causes a different colouring or opacification of these containers with the result that they can be readily identified during subsequent manual or automatic s eparation.
It should also be noted that for the purposes of the efficiency of the recycling operation as well as the production capacity of the machine, it is essential for the container treatment time to be high and for the rotary body to be able to contain a Large number of containers, both initial 1 y in bulk form, and subsequently in a separated and fully open condition.
A rotary body of considerable size is reauired for this purpose in which the containers may remain and be subject to thermohydraulic and mechanical treatment for a long period.
The machine of the invention may be embodied as a continuous or discontinuous machine.
Both versions are shown diagrammatically, purely by way of example, in the accompanying drawings, in whi ch:
Fig. 1 is a diagrammatic illustration in axial section through a machine of a conti nuous type;
Fig. 2 is a front view of the above machine from the left with respect to Fig. 1;
Figs. 3 to 5 show this machine in cross section along the lines III-III, IV-IV and V-V of Fig. 1 respectively;
Fig. 6 is a diagrammatic illustration in axial section through a machine of a discontinuous type;
Figs. 7 to 9 show this machine in cross section along the lines VII-VII, VIII-VIII and IX-IX respectively;
Fig. 10 is a diagrammatic axial section through a different loading zone for a machine of the continuous type as shown in Fig. 1.
Figs. 1 to 5 show a machine of the invention of the continuous type. It comprises a hollow body 1 of substantially cylindrical shape with suitably insulated walls 40 which is supported and: caused to rotate by a pair of motor-driven rollers 2 (Fig. 2) supported. by a base 3. The drive engagement between the rollers 2 and the rotary body 1 is provided at the location of reinforcing strips 4 of the rotary body.
As shown in Fig. 1, the hollow rotary body 1 has an inlet opening 5 and an outlet opening 6 for the material to be recycled. A loading duct 7 with a control valve 24 and a hopper S is provided at the inlet opening 5 and a discharge duct 9 with a control valve 25 and a hopper 10 with a ve!-tical opening is provided at the outlet opening 6.
A hydraulic duct 11 supported by a fixed frame 12 passes axially though the entire rotary body 1 from ~0 the inlet opening 5 almost as far as the outlet opening 6 for the supply of washing fluid at a predetermined temperature (for instance hot water, superheated water, steam) with or without chemical additives which is distributed within the rotary body ~5 I by spray nozzles I3. This fluid is then evacuated via apertures 14 and conveyed through ducts 41 to a collection tank (not shown) from which it is preferably taken for recycling in a system (not shown) comprising a pump, a vibrati ng screen, a 20 further collection tank and a heating and ;pumping unit which supplies it to the duct 11 via a duct 42.
The inner space of the rotary body 1 is divided into three sectors 15, 16 and 17 by two partitions 18 provided with large central holes 19 for the passage of the duct 11 and the material to be treated. The sector 15, which is closest to the inlet opening 5, houses floating spheres 20, for instance of elastomer, which are adapted to collide with the containers which have just been supplied in bulk in order to assist their separation. The intermediate sector l6 houses weights 21 connected by chains or other pliable suspension means 22 to the inner wall of the rotary body 1 or the hydraulic duet 11; these weights are adapted to complete, where necessary, the mutual separation of the containers, to facilitate the separation of the stoppers and to help to separate labels and bases which have already been partially separated from the containers as a result of the thermohydraulic action exerted by the washing fluid. The inner wall of the three sectors 15, 16 and 17 is finally provided with helically disposed agitating blades 23 which are adapted to keep the material moving during treatment and to convey it gradually to the discharge hopper 1C.
Figs. 6 to 9 show a machine of a discontinuous type.

The structure of this machine is substantially the same as that of the continuous machine with the exception that a single inlet and outlet opening 30 is provided, both the loading duct 7 and the discharge duct 9 being provided at this location; the discharge duct, prod ded with a large horizontal opening to allow improved access by the treated containers, is also used for the discharge of the washing fluid. Motorization is provided by a motor 31 and idler wheels 32 supported by the base 3 support the rotary body 1. Identical components, bearing the same reference numerals, are not described again.
This type of discharge with a large horizontal opening, particularly suited to containers of irregular shape and large dimensions, may be used with the machine of a continuous type described above.
This variant is shown in Fig. 10 where the discharge duct is shown by 43 and :its opening by 44, while the other reference nunerals are the same as those of corresponding structural components of Fig. 2.

As shown, the side wall of the hollow body 1 converges towards the opening 44 to facilitate the discharge of the containers.
A similar variant may be provided for the loading zone for the containers to be treated.

Claims (12)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. A machine for recycling plastic containers, the machine comprising a hollow rotary body rotated about a longitudinal substantially horizontal axis and provided with inlet and outlet means for the containers to be recycled, spraying means for supplying hot washing fluid into the rotary body, and mechanical impact means housed in the rotary body and actuated by rotation of the rotary body to collide with the containers to be recycled, wherein said hollow rotary body has a continuous lateral wall for retaining the washing fluid inside the rotary body during a recycling operation.
2. A machine as claimed in claim 1, wherein the mechanical impact means comprise agitator blades which are disposed helically along an inner surface of the lateral wall of the hollow rotary body.
3. A machine as claimed in claim 1 or 2, wherein the hollow rotary body has an inner space divided into adjacent communicating sectors, and wherein the mechanical impact means comprise moving bodies for striking the containers.
4. A machine as claimed in claim 3, wherein the moving bodies comprise floating spheres housed in a sector of the adjacent communicating sectors which is closest to an inlet opening for the material in the rotary body.
5. A machine as claimed in claim 3, wherein the moving bodies comprise suspended weights housed in an intermediate sector of the adjacent communicating sectors.
6. A machine as claimed in any one of claims 1 to 5, wherein the spraying means for supplying the washing fluid comprise nozzles for spraying the fluid onto the containers.
7. A machine as claimed in any one of claims 1 to 6, wherein the washing fluid contains chemical additives adapted to cause a different colouring or opacification of glue containers depending on the plastic material from which they are made.
8. A machine as claimed in any one of claims 1 to 7, wherein the hollow rotary body has an inlet opening and an outlet opening for the containers to be recycled so as to form a continuously operating machine.
9. A machine as claimed in claim 8, wherein the outlet opening is formed by a discharge duct with a large horizontal opening.
10.A machine as claimed in claim 9, wherein the hollow body has a side wall tapering towards the outlet opening of the discharge duct.
11. A machine as claimed in any one of claims 1 to 10, wherein the hollow rotary body has a single inlet and outlet opening for the containers to be recycled so as to form a discontinuously operating machine.
12. A machine as claimed in any one of claims 1 to 11, wherein the containers are bottles.
CA 2095930 1990-11-19 1991-11-09 Machine for recycling plastic containers, in particular bottles Expired - Lifetime CA2095930C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT22100A/90 1990-11-19
IT2210090A IT1245855B (en) 1990-11-19 1990-11-19 MACHINE FOR THE RECYCLING OF PLASTIC MATERIAL CONTAINERS, IN PARTICULAR BOTTLES
PCT/EP1991/002135 WO1992008591A1 (en) 1990-11-19 1991-11-09 Machine for recycling plastic containers, in particular bottles

Publications (2)

Publication Number Publication Date
CA2095930A1 CA2095930A1 (en) 1992-05-20
CA2095930C true CA2095930C (en) 2003-09-16

Family

ID=11191500

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2095930 Expired - Lifetime CA2095930C (en) 1990-11-19 1991-11-09 Machine for recycling plastic containers, in particular bottles

Country Status (12)

Country Link
US (1) US5390799A (en)
EP (1) EP0558528B1 (en)
JP (1) JP3057376B2 (en)
KR (1) KR0131684Y1 (en)
AT (1) ATE137157T1 (en)
AU (1) AU8877491A (en)
CA (1) CA2095930C (en)
DE (1) DE69119091T2 (en)
DK (1) DK0558528T3 (en)
ES (1) ES2086002T3 (en)
IT (1) IT1245855B (en)
WO (1) WO1992008591A1 (en)

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DE10002682A1 (en) * 2000-01-24 2001-08-02 Krones Ag Process for reprocessing PET components and device for carrying out the process
CA2359166C (en) * 2001-10-16 2008-07-08 Merlin Plastics Alberta Inc. Label release and separation system
US20080174102A1 (en) * 2007-01-22 2008-07-24 Mckinnon Lance Labeling liquids
IT1399363B1 (en) 2010-04-07 2013-04-16 Previero Sas METHOD AND EQUIPMENT FOR REMOVAL OF LABELS FROM CONTAINERS
CN102553870B (en) * 2011-09-21 2014-05-07 杭州富兴环保机械有限公司 Thermal washing machine for plastic bottles
CN102825047A (en) * 2012-08-24 2012-12-19 无锡绿科环保科技有限公司 Thermal washer for beverage bottles
ITMI20130615A1 (en) 2013-04-15 2014-10-16 Previero Sas METHOD AND EQUIPMENT FOR DRY REMOVAL OF LABELS FROM PLASTIC CONTAINERS
BE1021753B1 (en) 2013-12-10 2016-01-15 New Lime Development Sprl HYDRATED LIME COMPOSITION FOR THE TREATMENT OF SMOKE
US9968971B1 (en) * 2014-07-11 2018-05-15 Plastic Revolutions, Inc. Friction washer that cleans plastic for recycling
US20230219261A1 (en) * 2020-05-29 2023-07-13 The University Of Sydney A process for recycling a laminate and a solution therefor
CN112046960A (en) * 2020-07-20 2020-12-08 孙琦 Garbage classification device for plastic bottle recovery

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Also Published As

Publication number Publication date
EP0558528A1 (en) 1993-09-08
CA2095930A1 (en) 1992-05-20
DE69119091D1 (en) 1996-05-30
KR0131684Y1 (en) 1999-01-15
US5390799A (en) 1995-02-21
IT1245855B (en) 1994-10-25
DE69119091T2 (en) 1996-10-31
EP0558528B1 (en) 1996-04-24
DK0558528T3 (en) 1996-08-26
IT9022100A1 (en) 1992-05-20
ES2086002T3 (en) 1996-06-16
JP3057376B2 (en) 2000-06-26
WO1992008591A1 (en) 1992-05-29
AU8877491A (en) 1992-06-11
IT9022100A0 (en) 1990-11-19
ATE137157T1 (en) 1996-05-15
JPH06502134A (en) 1994-03-10

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