CA2063982A1 - Photosensitive composition based on acrylates - Google Patents
Photosensitive composition based on acrylatesInfo
- Publication number
- CA2063982A1 CA2063982A1 CA002063982A CA2063982A CA2063982A1 CA 2063982 A1 CA2063982 A1 CA 2063982A1 CA 002063982 A CA002063982 A CA 002063982A CA 2063982 A CA2063982 A CA 2063982A CA 2063982 A1 CA2063982 A1 CA 2063982A1
- Authority
- CA
- Canada
- Prior art keywords
- weight
- meth
- acrylate
- photosensitive composition
- aliphatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/04—Chromates
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
- B29C64/129—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
- B29C64/135—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0037—Production of three-dimensional images
Abstract
A liquid photosensitive composition comprising (1) 40 to 80 % by weight of a urethane (meth)acrylate having a functionality of 2 to 4 and a molecular weight (Mw) of 500 to 10 000, (2) 5 to 40 % by weight of a hydroxyl group containing aliphatic or cycloaliphatic di(meth)acrylate, (3) 0 to 40 % by weight of a mono(meth)acrylate or of a mono-N-vinyl compound having a Mw of not more than 500, (4) 0.1 to 10 % by weight of a photoinitiator, (5) 0 to 30 % by weight of an aliphatic or cycloaliphatic: di(meth)acrylate which differs from (2), of an aliphatic tri(meth)acrylate or of an aromatic di- or tri(meth)acrylate, and (6) 0 to 5 % by weight of customary additives, such that the proportion of components (1) to (6) together is 100 % by weight.
The composition is a photosensitive composition which can be polymerised by irradiation with actinic light and which is suitable for the production preferably.of three-dimensional objects by the stereolithographic technique.
The composition is a photosensitive composition which can be polymerised by irradiation with actinic light and which is suitable for the production preferably.of three-dimensional objects by the stereolithographic technique.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH93691 | 1991-03-27 | ||
CH19992 | 1992-01-23 | ||
CH199/92-4 | 1992-01-23 | ||
CH936/91-5 | 1992-01-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2063982A1 true CA2063982A1 (en) | 1992-09-28 |
CA2063982C CA2063982C (en) | 2002-05-28 |
Family
ID=25683853
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002063982A Expired - Fee Related CA2063982C (en) | 1991-03-27 | 1992-03-25 | Photosensitive composition based on acrylates |
Country Status (7)
Country | Link |
---|---|
US (1) | US5476749A (en) |
EP (1) | EP0506616B1 (en) |
JP (1) | JP3252331B2 (en) |
KR (1) | KR100199479B1 (en) |
CA (1) | CA2063982C (en) |
DE (1) | DE59209143D1 (en) |
HK (1) | HK1005630A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995013565A1 (en) * | 1993-11-10 | 1995-05-18 | W.R. Grace & Co.-Conn. | Photosensitive compositions useful in three-dimensional part-building and having improved photospeed |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW418346B (en) * | 1993-03-05 | 2001-01-11 | Ciba Sc Holding Ag | Photopolymerisable compositions containing tetraacrylates |
US5496682A (en) * | 1993-10-15 | 1996-03-05 | W. R. Grace & Co.-Conn. | Three dimensional sintered inorganic structures using photopolymerization |
WO1995012146A1 (en) * | 1993-10-26 | 1995-05-04 | Toray Industries, Inc. | Dry lithographic forme |
DE4424101A1 (en) * | 1994-07-08 | 1996-01-11 | Basf Lacke & Farben | Radiation-curable lacquers and their use in the production of matt lacquer films |
JP3117394B2 (en) * | 1994-11-29 | 2000-12-11 | 帝人製機株式会社 | Optical three-dimensional molding resin composition |
GB9504995D0 (en) * | 1995-03-11 | 1995-04-26 | Zeneca Ltd | Compositions |
RU2074673C1 (en) * | 1995-06-01 | 1997-03-10 | Межотраслевой научно-технический комплекс "Микрохирургия глаза" | Elastic artificial crystalline lens and method for manufacturing same |
JPH0971707A (en) * | 1995-06-29 | 1997-03-18 | Takemoto Oil & Fat Co Ltd | Photocurable composition for plastic mold and plastic mold |
EP0763779A3 (en) * | 1995-09-18 | 1997-07-30 | Mitsubishi Chem Corp | Unsaturated group-containing urethane compound, photopolymerizable composition containing it, and photosensitive lithographic printing plate |
EP0802455B1 (en) * | 1996-04-15 | 2002-10-16 | Teijin Seiki Co., Ltd. | Use of a photocurable resin composition for the production of a stereolithographed object |
WO1997042549A1 (en) | 1996-05-09 | 1997-11-13 | Dsm N.V. | Photosensitive resin composition for rapid prototyping and a process for the manufacture of 3-dimensional objects |
US5910979A (en) * | 1997-10-20 | 1999-06-08 | At&T Corp. | Method for billing local communication services provided by an interexchange communication network |
US6201036B1 (en) * | 1998-07-21 | 2001-03-13 | Mezhoiraslevoi Nauchno-Tekhnichesky Komplex “Mikrokhirurgia Glaza” | Light-curable polymer material, method for making an elastic intraocular lens, and an elastic intraocular lens |
US6187374B1 (en) | 1998-09-02 | 2001-02-13 | Xim Products, Inc. | Coatings with increased adhesion |
DE19851567A1 (en) * | 1998-11-09 | 2000-05-11 | Emtec Magnetics Gmbh | Binder composition for magnetic recording media and photoinitiator mixture curable by UV radiation |
JP3855929B2 (en) | 2000-05-29 | 2006-12-13 | 日立化成工業株式会社 | Photosensitive resin composition, photosensitive element, method for producing resist pattern, and method for producing printed wiring board |
JP2002148802A (en) * | 2000-11-07 | 2002-05-22 | Tokyo Ohka Kogyo Co Ltd | Photosensitive composition for sandblast and photographic sensitive film using the same |
US6811937B2 (en) | 2001-06-21 | 2004-11-02 | Dsm Desotech, Inc. | Radiation-curable resin composition and rapid prototyping process using the same |
US20040054025A1 (en) * | 2002-06-20 | 2004-03-18 | Lawton John A. | Compositions comprising a benzophenone photoinitiator |
FR2856145B1 (en) * | 2003-06-16 | 2005-09-02 | Michelin Soc Tech | DETECTION OF THE REVOLUTIONS OF A PNEUMATIC ASSEMBLY AND WHEEL, USING THE TERRESTRIAL MAGNETIC FIELD. |
US7375144B2 (en) * | 2005-06-16 | 2008-05-20 | Eastman Chemical Company | Abrasion resistant coatings |
KR100771367B1 (en) | 2005-07-25 | 2007-10-30 | 주식회사 엘지화학 | Resin having excellent mechanical physical property, and photosensitive composition comprising the same |
JP5063127B2 (en) * | 2007-02-06 | 2012-10-31 | 株式会社Adeka | Polymerizable optically active compound and polymerizable composition containing the polymerizable optically active compound |
US20110201717A1 (en) * | 2007-12-28 | 2011-08-18 | E. I. Du Pont De Nemours And Company | Actinically curable adhesive composition |
KR20100112149A (en) * | 2007-12-28 | 2010-10-18 | 이 아이 듀폰 디 네모아 앤드 캄파니 | Thermally and actinically curable adhesive composition |
CN109956682B (en) | 2011-02-18 | 2022-05-17 | 肖特公开股份有限公司 | Solder glass, insulating sleeve and device comprising insulating sleeve |
CN103361021A (en) * | 2013-07-24 | 2013-10-23 | 吴波 | Optical transparent adhesive with low shrinkage |
JP6337523B2 (en) * | 2014-03-07 | 2018-06-06 | 東洋インキScホールディングス株式会社 | Active energy ray polymerizable resin composition and laminate |
ITUB20154169A1 (en) | 2015-10-02 | 2017-04-02 | Thelyn S R L | Self-lubricating substrate photo-hardening method and apparatus for the formation of three-dimensional objects. |
EP3658602A4 (en) | 2017-07-25 | 2021-04-14 | 3M Innovative Properties Company | Photopolymerizable compositions including a urethane component and a reactive diluent, articles, and methods |
US11904031B2 (en) | 2017-11-22 | 2024-02-20 | 3M Innovative Properties Company | Orthodontic articles comprising polymerized composition comprising at least two free-radical initiators |
CN111372959B (en) | 2017-11-22 | 2022-09-02 | 3M创新有限公司 | Photopolymerizable compositions, articles, and methods comprising a urethane component and a monofunctional reactive diluent |
JP7015682B2 (en) * | 2017-12-06 | 2022-02-03 | ナガセケムテックス株式会社 | Resin composition for stereolithography |
US11616302B2 (en) | 2018-01-15 | 2023-03-28 | Rogers Corporation | Dielectric resonator antenna having first and second dielectric portions |
US11633908B2 (en) * | 2018-03-02 | 2023-04-25 | Formlabs, Inc. | Latent cure resins and related methods |
KR20210005628A (en) | 2018-04-20 | 2021-01-14 | 디에스엠 아이피 어셋츠 비.브이. | Radiation curable composition for additive manufacturing |
EP3813764A2 (en) | 2018-06-29 | 2021-05-05 | 3M Innovative Properties Company | Orthodontic articles prepared using a polycarbonate diol, polymerizable compositions, and methods of making the articles |
JP7010455B2 (en) | 2018-06-29 | 2022-01-26 | スリーエム イノベイティブ プロパティズ カンパニー | Orthodontic articles prepared using polycarbonate diol and its manufacturing method |
CN112367959A (en) | 2018-06-29 | 2021-02-12 | 3M创新有限公司 | Orthodontic articles comprising cured free-radically polymerizable compositions having improved strength in aqueous environments |
US11225535B2 (en) | 2018-06-29 | 2022-01-18 | 3M Innovative Properties Company | Photopolymerizable compositions including a polyurethane methacrylate polymer prepared using a polycarbonate diol, articles, and methods |
GB201814535D0 (en) | 2018-09-06 | 2018-10-24 | Uea Enterprises Ltd | Intraocular devices |
US11552390B2 (en) | 2018-09-11 | 2023-01-10 | Rogers Corporation | Dielectric resonator antenna system |
GB2594171A (en) | 2018-12-04 | 2021-10-20 | Rogers Corp | Dielectric electromagnetic structure and method of making the same |
CN113906066A (en) * | 2019-05-30 | 2022-01-07 | 罗杰斯公司 | Photocurable composition for stereolithography, stereolithography method using the same, polymer assembly formed by stereolithography method, and device comprising the polymer assembly |
US20230002631A1 (en) | 2019-11-07 | 2023-01-05 | Basf Se | Water-washable compositions for use in 3d printing |
US11482790B2 (en) | 2020-04-08 | 2022-10-25 | Rogers Corporation | Dielectric lens and electromagnetic device with same |
US11413819B2 (en) | 2020-09-03 | 2022-08-16 | NEXA3D Inc. | Multi-material membrane for vat polymerization printer |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4100141A (en) * | 1976-07-02 | 1978-07-11 | Loctite (Ireland) Limited | Stabilized adhesive and curing compositions |
US4575330A (en) * | 1984-08-08 | 1986-03-11 | Uvp, Inc. | Apparatus for production of three-dimensional objects by stereolithography |
US4789620A (en) * | 1986-03-03 | 1988-12-06 | Mitsubishi Rayon Co. Ltd. | Liquid photosensitive resin composition containing carboxylated epoxy acrylates or methacrylates |
EP0286594A2 (en) * | 1987-04-06 | 1988-10-12 | Ciba-Geigy Ag | Process for the production of photographically structurable coatings |
EP0378144B1 (en) * | 1989-01-10 | 1995-03-08 | Ciba-Geigy Ag | Photocurable compositions |
DE59010008D1 (en) * | 1989-10-27 | 1996-02-08 | Ciba Geigy Ag | Photosensitive mixture |
-
1992
- 1992-03-19 EP EP92810201A patent/EP0506616B1/en not_active Expired - Lifetime
- 1992-03-19 DE DE59209143T patent/DE59209143D1/en not_active Expired - Fee Related
- 1992-03-25 CA CA002063982A patent/CA2063982C/en not_active Expired - Fee Related
- 1992-03-26 KR KR1019920005148A patent/KR100199479B1/en not_active IP Right Cessation
- 1992-03-27 JP JP11513692A patent/JP3252331B2/en not_active Expired - Fee Related
-
1994
- 1994-09-09 US US08/303,563 patent/US5476749A/en not_active Expired - Lifetime
-
1998
- 1998-06-02 HK HK98104761A patent/HK1005630A1/en not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995013565A1 (en) * | 1993-11-10 | 1995-05-18 | W.R. Grace & Co.-Conn. | Photosensitive compositions useful in three-dimensional part-building and having improved photospeed |
US5418112A (en) * | 1993-11-10 | 1995-05-23 | W. R. Grace & Co.-Conn. | Photosensitive compositions useful in three-dimensional part-building and having improved photospeed |
Also Published As
Publication number | Publication date |
---|---|
EP0506616B1 (en) | 1998-01-21 |
HK1005630A1 (en) | 1999-01-15 |
KR100199479B1 (en) | 1999-06-15 |
EP0506616A1 (en) | 1992-09-30 |
US5476749A (en) | 1995-12-19 |
KR920018522A (en) | 1992-10-22 |
JPH05224412A (en) | 1993-09-03 |
CA2063982C (en) | 2002-05-28 |
DE59209143D1 (en) | 1998-02-26 |
JP3252331B2 (en) | 2002-02-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |