CA1333572C - High gloss, high-shine lipstick - Google Patents

High gloss, high-shine lipstick

Info

Publication number
CA1333572C
CA1333572C CA000597333A CA597333A CA1333572C CA 1333572 C CA1333572 C CA 1333572C CA 000597333 A CA000597333 A CA 000597333A CA 597333 A CA597333 A CA 597333A CA 1333572 C CA1333572 C CA 1333572C
Authority
CA
Canada
Prior art keywords
lipstick
isohexadecane
weight percent
composition
gloss
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA000597333A
Other languages
French (fr)
Inventor
Robert John Edmundson
Terry Clifton Jacks
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Intellectual Property Holding Co
Original Assignee
Intellectual Property Holding Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Intellectual Property Holding Co filed Critical Intellectual Property Holding Co
Application granted granted Critical
Publication of CA1333572C publication Critical patent/CA1333572C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06Lipsticks
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S424/00Drug, bio-affecting and body treating compositions
    • Y10S424/05Stick

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

A lipstick composition comprising from 0.5 to 8 weight percent isohexadecane in a conventional lipstick formulation. The inventive lipsticks have a very high gloss, not attainable with prior-art lipsticks.

Description

133357 ~

Case 1697 FTE

HIGH-GLOSS, HIGH-SHINE LIPSTICK

BACKGROUND OF THE INVENTION
This invention relates to lipstick compositions and, in particular, to lipstick compositions having very high gloss when applied to the lips.
Prior art lipsticks comprise a molded solid fatty base containing dissolved and suspended dyes, preservatives, and optional fragrance in admixture with cosmetically acceptable waxes, oils, solids and semisolids. M.G. deNavarre in chapter 44 entitled "Lipstick" of "The Chemistry and Manufacture of Cosmetics", Vol. IV, 2nd Edition, Continental Press, 1975, p 767-840 discloses at page 769 that the most preferred base materials, excluding dyes preservative and fragrance, are the cosmetic waxes: beeswax, Candelilla wax, Carnauba wax and ozokerite as well as the cosmetic oils: castor oil and lanolin. DeNavarre discloses that beeswax adds binding and molding properties to lipstick;
Candellila wax gives lipstick hardness, rigidity and gloss; and Carnauba wax and ozokerite give molded lipstick toughness; castor oil is solvent for the dyes as well as an emollient; and lanolin aids in making and maintaining molded lipstick as a homogeneous mass as well as serving as an emollient. Among the other numerous materials useful for a lipstick, deNavarre discloses that branched chain compounds such as fatty alcohols and fatty acid esters have been found to be useful in cosmetic products because of the ability of such branched-chain compounds to maintain a porous fatty film on the lips.
However, branched-chain alkanes and alkenes such as pristane and squalene, respectively have found very limited use in lipsticks. Pristane causes excessive softness, and squalene tends to impart an unpleasant odor.
There is no prior disclosure that isohexadecane would be a gloss-enhancing agent in a lipstick.
Isohexadecane is not listed in the third edition of the CTFA Cosmetic Ingredient Dictionary.

SUMMARY OF THE INVENTION
The present invention may be summarized as a lipstick composition comprising from 0.5 to 8 weight percent isohexadecane in a conventional lipstick formulation. Preferably, the composition contains 3.5 to 5 weight percent isohexadecane, and most preferably about 5 weight percent. The inventive lipsticks may be formulated with at least two distinctly different colored dyes which are heterogeneously mixed to form a unitary lipstick composition.
We have discovered that admixing isohexadecane with a conventional lipstick formulation surprisingly produces a high-gloss, high-shine lipstick. We believe that the gloss of our lipsticks exceeds that of prior-art lipsticks.

DETAILED DESCRIPTION OF THE INVENTION
Isohexadecane is available from The Permethyl Corporation, 15 Lee Blvd., Frazer, PA 19355 under the tradename Permethyl 101A~. It is comprised primarily of 2,2,4,4,6,6,8-heptamethyl nonane, but other branched-chain isomers of n-hexadecane are believed operable.

1333~7~

We have discovered that by lowering the amount of castor oil in the lipstick formulation and adding a gloss-enhancing amount of isohexadecane in accordance with this invention, a high shine, high gloss lipstick composition results. The lipstick compositions prepared in accordance with the present invention exhibit higher gloss and higher shine than conventional prior art lipsticks of similar composition which do not contain isohexadecane. The present invention is not limited to use in any one lipstick formulation but includes use in conventional lipstick formulations containing cosmetically acceptable waxes, oils, solid and semisolids in admixture with cosmetically acceptable colorants, and optionally one or more preservatives, antioxidants, flavoring agents and sweetners. Definition and suppliers of the ingredients in the following lists and in the example may be found in the third edition of the CTFA
Cosmetic Ingredients Dictionary, published by the Cosmetic, Toiletry, and Fragrence Association, Inc., 1110 Vermont Avenue, N.W., Washington, D.C. 20005 U.S.A. If any ingredients are not available, substitutions may be made, since it is believed that the incorporation of 0.5 to 8 weight percent isohexadecane will improve the shine and gloss when formulated into any conventional lipstick composition.
Typical suitable cosmetic waxes include ozokerite, lanolin alcohol, paraffin wax, bayberry wax, Polawax~ (a reaction product of higher fatty alcohols and ethylene oxide available from Croda, Inc., New York, NY
10016), trihydroxystearin, lanolin wax, beeswax, beeswax substitute (a mixture of paraffin and candellila wax and hydrogenated tallon glycerides and stearic acid and celylalcohol, available from Frank B. Ross Co., Inc., 6-10 Ash Street, Jersey City, NJ 07304), Candellila wax, microcrystalline wax, Carnauba wax, stearyl alcohol, 1333~7~

spermaceti, cocoa butter, fatty acids of lanolin, mono-, di- and triglycerides which are solid at 25C, e.g., glyceryl tribehenate (a triester of behenic acid and g y r ne) and C18-C36 acid triglyceride (a mixture of triesters of C18-C36 carboxylic acids and glycerine available from Croda, Inc., New York, NY under the tradenames Syncrowax HRC~ and Syncrowax HGL-C~
respectively, fatty esters which are solid at 25C, silicone waxes such as methyloctadecane-oxypolysiloxane and poly (dimethylsiloxy) stearoxysiloxane, stearyl mono-and diethanolamide, rosin and its derivatives such as the abietates of glycol and glycerol, hydrogenated oils solid at 25C, and sucroglycerides.
Typical suitable cosmetic oils include mineral oil, Purcellin oil, perhydrosqualene, castor oil, polybutene, odorless mineral spirits, sweet almond oil, avocado oil,, calophyllum oil, ricin oil, vitamin E
acetate, olive oil, silicone oils such as dimethicone, dimethylpolysiloxane and cyclomethicone, linolenic alcohol, oleyl alcohol, the oil of cereal germs such as the oil of wheat germ, isopropyl palmitate, isopropyl myristate, butyl myristate, hexadecyl stearate, butyl stearate, decyl oleate, acetyl glycerides, the octanoates and benzoates of (C12-C15) alcohols, the octanoates and decanoates of alcohols and polyalcohols such as those of glycol and glycerol, ricin oleates of alcohols and poly alcohols such as those of isopropyl adipate, hexyl laurate and octyl dodecanoate.
Typical suitable cosmetic solids or semi-solids include lanolin, hydrogenated lanolin, hydroxylated lanolin, acetylated lanolin, petrolatum, isopropyl lanolate, cetyl myristate, myristyl myristate, myristyl lactate, cetyl alcohol, stearyl alcohol, isostearyl alcohol and isocetyl lanolate.

133~

Typical suitable colorants employed in the cosmetic compositions of the present invention are the U.S. Government certified colors, both Drug and Cosmetic grade and Food, Drug and Cosmetic grade, e.g., D & C
reds, oranges, yellows and blues. The pigments employed are generally inorganic pigments such as iron oxides, titanium dioxides, or other conventional pigments approved for cosmetic use. The dyes and pigments are preferably employed in an amount ranging from about 1% to about 10% by weight of the formulation with about 2% to about 4% being more preferred.
Typical suitable preservatives include the lower alkyl esters of para-hydroxybenzoates (paraben) especially, methyl paraben, ethyl paraben, n-propyl paraben, n-butyl paraben, isobutyl paraben and mixtures thereof, imidazolidinyl urea, or diazolidinyl urea. The color pigments or coloring materials, e.g., organic dyes and inorganic pigments are usually dispersed in castor oil.
Typical suitable antioxidants include propyl, octyl and dodecyl esters of gallic acid, butylated hydroxyanisole, i.e., BHA, which is a mixture of 3-tert-butyl-4-hydroxyanisole (major) and 2-tert-butyl-4-hydroxyanisole, butylated hydroxytoluene and nordihydroguaiaretic acid.
Typical suitable flavoring agents include those approved by The Fragrance Institute such as chocolate fudge flavor available from Noville Essential Oil Co., North Bergen, NJ 07047 as well as others available from International Flavors and Frangrances, New York, NY.
Typical suitable sweeteners include sucrose, corn syrup, saccharin and asparatame. The sweeteners are normally dissolved in water and dipropylene glycol is added before use in the lipstick compositions of the present invention.

1333~72 It is preferred to employ a mixture of these cosmetic ingredients for their different functions, for example oleyl alcohol is a penetrant and color vehicle, castor oil is a color dispersing agent, mineral oil and cyclomethicone are emollients and moisturizers.
A lipstick base formulation may be prepared in a stirred tank to which is added a gloss-enhancing amount of isohexadecane and a mixture of cosmetically acceptable waxes, oils, solids and/or semi-solids, preferably free of dyes and pigments, preservatives and fragrance. If desired, different lipstick base formulations may be prepared for each separate dye or colorant to be used in the final lipstick composition. Regardless of how the lipstick based formulations are prepared, it is desirable that the base formulations for each different color have substantially similar consistencies to enable production of a uniform lipstick product when combined. After the base formulations are prepared, individual portions thereof are forwarded to separate color mixing tanks to which at least two distinctly different colored dyes and/or pigments are added, with mixing. After a homogeneous mixture is formed, flavoring and sweetener are added and mixing is continued until a homogeneous mixture is formed. The separate colored lipstick compositions may be then poured into molds. In a preferred aspect of this invention, lipstick compositions containing at least two distinctly different colored dyes and/or pigments are blended together under laminar-flow conditions in a funnel-shaped heterogenous blender by known methods, e.g., in accordance with the procedure of U.S. Patent No. 3,201,314 at col. 2 lines 64 to col. 3 line 43 to form an integral multi-colored lipstick.

1333~7~

The following example illustrates but does not limit the invention.

Example Fudge Swirl Lipstick This lipstick is prepared in differently colored parts, a chocolate brown part and a white part.
The two parts are blended under conditions of laminar flow to produce a two color lipstick.

Chocolate Brown Part Ingredient Weight Percent Part A
Beeswax Substitutel 7.200 Candellila Wax SP 5.000 Carnuaba Wax SP 4.400 Ozokerite 170 MF 1.400 Acetylated Lanolin Alcohols 14.900 Hydrogenated Vegetable Oil 7.000 Lanolin Oil 14.900 Diisopropyl Dimerate 1.750 Mineral Oil, Light Carnation 8.300 Polybutene 8.800 Methyl Paraben 0.100 Propyl Paraben 0.200 Butyl Paraben - 0.100 13335r~ ?i~

Part B
Isohexadecane 5.000 Part C
Extender Yellow #5 _ (30%)2 0.830 Extender Red Oxide _ (30%)2 0.415 Ingredient Weight Percent Extender Red #7 _ (30%)2 0.707 Extender Blue #1 _ (30%)2 0.269 Extender Red #6 _ (30%)2 0.415 Extender T102 - (50%)3 0.145 Part D
Fudge Chocolate Flavor 4.000 Part E
Sacharin 0.250 Water 0.350 Dipropylene Glycol 1.000 Part F
Castor Oil q.s. ad 100%

1 paraffin and candelilla wax and hydrogenated tallow glycerides and stearic acid and cetyl alcohol.
2 30% by weight in castor oil.
3 50% by weight in castor oil.
Melt all the solid ingredients of Part A in a steam-jacketed stainless steel kettle equipped with a double agitator stirrer at a temperature of 85C; add remaining ingredients in Part A and stir until a homogeneous mixture is formed. Add isohexadecane thereto 1333~7~

and mix. Add to the so-formed mixture a mixture of the ingredients of Part C; stir until a homogeneous admixture is formed.
Cool the so-formed mixture to 45C and add thereto the ingredients in Parts D and E. Heat to 60C, add the castor oil and stir until a homogeneous mixture is formed.

White Part Ingredient Weight Percent Part A
Beeswax Substitute 7.200 Candellila Wax SP 5.000 Carnuaba Wax SP 4.400 Ozokerite 170 MF 1.400 Acetylated Lanolin Alcohols14.900 Hydrogenated Vegetable Oil7.000 Lanolin Oil 14.900 Diisopropyl Dimerate 1.750 Mineral Oil, Light Carnation8.300 Polybutene 8.800 Methyl Paraben 0.100 Propyl Paraben 0.200 Butyl Paraben 0.100 BHA 0.050 Part B
Isohexadecane S.000 Part C
Extender, Tio2 (50%) 1.500 1333~72 Part D
Saccharin 0.250 H2O 0.350 Dipropylene Glycol 1.000 Part E
Chocolate Fudge Flavor 4.000 Ingredient Weight Percent Part F
Castor Oil q.s. ad 100%

The procedure for the preparation of the chocolate brown part outlined above was used to form the white part.
The molten masses of the chocolate brown and white portions of the Fudge Swirl lipstick are blended together in equal amounts to produce a marbilized high gloss high shine lipstick. The blending is accomplished in known apparatus, e.g., that shown in Figure 1 of U.S.
Patent No. 3,201,314 in accordance with the procedure described at Col. 2, line 64 to Col. 3, line 31.
The brown-white marbilized lipstick so formed has higher-gloss and higher-shine on a visual comparison with a lipstick of similar composition without isohexadecane.

same ingredient as used in chocolate brown part.

Claims (9)

1. A lipstick composition comprising from 0.5 to 8 weight percent isohexadecane in a conventional lipstick formulation.
2. The lipstick composition of claim comprising from 3.5 to 5 weight percent isohexa-decane.
3. The lipstick composition of claim 1 comprising 5 weight percent isohexadecane.
4. The lipstick composition of claim 1, 2 or 3, wherein the lipstick formulation comprises at least two distinctly different colored dyes which are heterogeneously mixed to form a unitary lipstick composition.
5. The lipstick composition of claim 1, 2 or 3, wherein the lipstick formulation further comprises a flavoring agent.
6. An integral multi-colored lipstick com-position comprising a gloss-enhancing amount of isohexadecane in admixture with a lipstick formula-tion containing a heterogeneous mixture of at least two distinctly different colored dyes.
7. A method of producing a high gloss lip-stick which comprises admixing a lipstick formulation containing from 0.5 to 8 weight percent hexadecane.
8. The method of claim 7, wherein the result-ing lipstick formulation contains from 3.5 to 5 weight percent isohexadecane.
9. The method of claim 7, wherein the result-ing lipstick formulation contains 5 weight percent isohexadecane.
CA000597333A 1988-04-22 1989-04-20 High gloss, high-shine lipstick Expired - Fee Related CA1333572C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/184,995 US4873078A (en) 1988-04-22 1988-04-22 High-gloss, high-shine lipstick
US184,995 1988-04-22

Publications (1)

Publication Number Publication Date
CA1333572C true CA1333572C (en) 1994-12-20

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CA (1) CA1333572C (en)

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