CA1294454C

CA1294454C - Leather, in particular split leather provided with a dressing as well asprocess and apparatus for producing dressed leather

Info

Publication number: CA1294454C
Application number: CA000492265A
Authority: CA
Inventors: Philipp Schaefer
Original assignee: MICROPLASTIC CORP.
Current assignee: MICROPLASTIC CORP
Priority date: 1984-10-06
Filing date: 1985-10-04
Publication date: 1992-01-21
Anticipated expiration: 2009-01-21
Also published as: DE3436751C2; EP0178294A3; EP0178294A2; DE3581040D1; ATE59680T1; US4983245A; ES547615A0; DE3436751A1; EP0178294B1; US4923732A; DE3584451D1; ES8700327A1

Abstract

ABSTRACT OF THE DISCLOSURE
A dressed leather is provided at least on one side with depressions and have on this side absorbent protruding fibres.
At this side the leather is bonded with a layer formed of an aqueous dispersion of synthetic plastics material, said layer fills the depressions and completely receives the protruding fibres and formes at least a part of the dressing, which dressing is provided with a structured surface at the side turned away from the leather.
Preferably, the dressing consists of two layers, the inner layer, which is adjacent the leather and completely receives the protruding fibres, is formed of the aqueous dispersion of synthetic plastics material and the outer layer, which has the structured surface, consists of an aqueous dispersion of synthetic plastics material or of a liquid solution of synthetic plastics material.

Description

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Leather, in particular split leather provided with a dressing as well as process and apparatus for producing dressed leather BACKGROUND AND SUMMARY OF THE INVENTION

The invention refers to a leather, in particular a split leather,being provided at at least one side with depressions and having at at .least one side absorbent pro-truding fibres and being provided on this side with adressing. The term "leather" is to comprise also materials comprising leather fibres.
The invention further refers to a process for dressing such a leather, in particular split leather, as well as to an apparatus for produclng dressed leather, in particular split leather.
It is already known to provide split leather with a dressing having a structured surface, for example ~a surface structured like leather graln. In this case, a llquld and wet compound forming the dressing is directly applied to the top surface of the split leather, for example by pouring, spreading, rolling, spraying or printing:, or by a roller coating machine, and then solidif~ied by drylng. For giving the dressing the structured surface of leather grain,.the :
dressed split`leather must be embossed after having dried the liquid dressing compound.or,~:respectively,~aEter having solidified the dressing. Such~embossing of the split leath.er :

is effected in an embossing press under the action of heat and of a very high pressure. The structure of the split leather and of the dressing is thereby changed in an un-desired manner. The thickness of the dressed split leather is not only reduced but the hardness and stiffness of the split leather is also increased. Furthermore, the steam--permeability, if at all existing, of the dressing is reduced or destroyed, because during the embossing operation the pores existing within the dressing are again closed or destroyed, respectively, under the action of heat and pressure.
A substantial drawback of this known process resides in the fact that, for producing the dressing only thermo-plastic materials deformable unde-r the action of heat and pressure can be used, because otherwise subsequent pro-duction of the structured surface by subsequently embossing the solidified dressing would not be possible. Such thermo-plastic synthetic plastics materials have, however, worse properties than non-thermoplastic or less thermoplastic materials.
It is an additional drawback that producti~n of the structured surface by embossing must be effected in a separate process step, which means that the dressed split leather must be further treated, i.e. must, as a rule, manually be inserted into an embossing press.
It is also known to apply the liquid dressing compound not directly onto the split leather but in several layers onto a support being provided with an anti-adhesive coating ~ 4~S4 and having a surface corresponding to the desired structure, noting that the split leather is placed on the last layer still being wet and that subsequently the thus dressed split leather is pressed within a roll press and/or is subjected to a vacuum treatment. When proceeding in this manner, an undesired rigidifying and undesired increase in hardness and an undesired reduction of the thickness of the dressed split leather is substantially avoided, but the bond strength between the dressing and the split leather is reduced.
Further, it has already been proposed to first apply part of the dressing onto a supporting base and to allow solidification of the dresslng and to apply a further part of the dressing onto one side of the spllt leather and to place this split leather with the dressing compound applied thereon still being wet onto the supporting base such that the side of the split leather belng provided wlth the dressing rests on the~solidified dressing applied onto the supporting base and that the dry side of the split leather having no dressing applied thereon shows in upward direction.
The supporting base has, in this~case, the negative shape of the desired surface of the dressing having the appearance of leather grain,~ so that on drying the dressing compound under the action of low pressure the dressing lS given an appearance similar to that~of leather grain. When proceeding 25 in such a manner, the dressing is structured such that the thickness, the softness and the steam permeability of the split leather are not or scracely changed. Dressed split -`` 12~4~4 leathers produced in such a manner thus are scft, supple and have an appearance and properties most similar to that of full-grainy leather. The substantial drawback of this known procedure resides, however, in the fact that the split leather must manually be turned upside down immediately after having applied the wet dressing compound for fully contacting with the supporting base, having a corresponding structure, that side of the split leather having been provided with the dressing compound and facing downwardly. In par-ticular in connection with split leather of great surfaceextent, manually turning over results in considerable difficulties and in great physical stress. Furthermore, air is included between the supporting base and the side of the split leather being provided with the dressing when manually turning over the spIit~leather and placing same onto the supporting base, which substantially impairs the bonding strength of the dressing and the appearance of the dressing provided with the structure similar to leather grain at those areas where the air inclusions are present. This appearance is further impaired by damaging the still wet dressing when grlpping the split leather for manually turning over same and by the necessity of subsequent shifting the split leather when it has not been placed on the supporting base in the correct position.
It is an object of the pr-esent invention to provide a dressed leather in which the dressing having a structured surface can be made very thin but in which an inseparable . ,~, . .; :
' ~ ~5 -bond between the leather and the dressing is reliably pro-vided. It is a further object of the present invention to provide a dressed leather in which the excellent properties of natural leather, such as for example its steam-permeabili-ty are maintained. It is a further object of the inventionto provide a dressed leather which has a nice appearance with respect to shape, noting that the surface of the dressing can be shaped such that it fully corresponds to the appearance of a natural leather. Further, a dressed leather shall be provided, in which, on tensioning, the visible sur-face of the dressing is not changed in an undesired manner and, above all, the dressing is not peeled off the leather.
A further object of the invention is to design the leather such that the coarse fibrous structure, in particular split leather, is not marked on the surface of the dressing.
In addition, it is an object of the present invention to provide a process and an apparatus which allow to produce a dressed leather in a simple and reliable manner. In par-ticular, continuous production according to a conveyor-line system shall be possible. It is a stIll further object of the invention to reduce as fas as possible the operations becoming necessary when changing the color of the dressing.
In ganeral terms, the pre6ent invention relates to a ~plit leather pro~ided with a dressing which consist6 of 2~ two layers connected with each other, said layers compri~ing an inner, substantially non-thermoplastic layer immediately neighbouring the split leathsr and .

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completely absorbing fibers protruding f~om the split leather, this inner layer being made o~ an aqueous dispersion of cross-linkable synthetic plastics material and having a porous or foamy structure, this inner layer together with the embedded fibers having a density below lg/cm3, and an outer layer connected ~o the inner layer and being made of a liquid cross-linkable synthetic plastics material containing polyurethane, said outer layer having on its outer side a textured surface and having a greater density and hardness than the inner layer.
According to one feature of the present invention, the outer layer comprises the textured surface which is formed from an aqueous dispersion comprising polyurethane.
According to another feature, the outer layer comprises a textured surface formed from a liquid solution comprising polyurethane.
According to a further feature, the inner layer located adjacent the leather is made neutr~l with respect to colour relative to the leather and relative to the outer layer comprising the textured surface, the pigments or, respectively, dye stuffs being incorporated into the outer layer and defining the colour shade of the dressing.
BRIEF DESCRIPTION OF THE DRAWINGS
In the anne~ed drawings, the invention is schematically illustrated with reference to embodiments.
Figure 1 shows a side elevation of a first embodiment of a part of the apparatus according to the invention.
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Figure 2 shows a side elevation of a second embodiment of a part of ~he apparatus according to the invention.
Figure 3 shows a modified embodiment according to Figure 1.
Figure 4 shows a detail of the embodiment according to Figure 3 in an enlarged scale.
Figure 5 shows in an enlarged scale a dressed split leather provided with a dressing consisting of a single layer.
Figure 6 shows in an enlarged scale an inventive split leather comprising a dressing formed of two layers.
Figure 7 shows in a top plan view a third embodiment of a part of the apparatus according to the invention.
Figure 8 schematically shows in a top plan view an inventive apparatus allowing working according to a con-veyor-line process.
Figure 9 shows in a top plan view-a first embodiment of a vacuum device forming part of the apparatus according to the invention.
Figure 10 shows a section along the line X-X in Figure 9.
Figure 11 shows a side elevation of a second embodi-ment of the vacuum device.
Figure 12 shows ~a section along the line XII-XII in Figure 11.
Figure 13 shows a side elevatlon of a third embodiment of the vacuum device.

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- DETAILED DESCRIPTION OF THE DRAWINGS
The part, shown in Figure 1, of the apparatus according to the invention has a supporting means 1 for the leather to be dressed, which is formed of a split leather 3. The supporting means is formed of an endless driven belt being passed over two rolls 5. The split leather 3 is placed onto the belt 1 and the dressing 4 consisting of an aqueous dispersion of synthetic plastics material is uniformely applied by means of a coating roll 6 while the split leather is passed by below the coating roll 6. The coating roll 6 rotates, as is indicated by arrows, in opposite direction to the direction of movement of the belt forming the supporting means 1.
This makes sure thatr by making use of the shearing forces, the fibres protruding from the split leather 3 are completely embedded within the aqueous dispersion of synthetic plastics material applied in a single oper.~ting step and are thus inseparably bonded to this layer after solidificatlon of -this aqueous dispersion of synthetic plastics material.
In place of the coating ro.ll 6 rotating in opposite sense, also a pouring device can ~e used, via whlch the dressing 4 consisting of an.aqueous dispersion of synthetic plastics material is applied onto the split leather 3 whlle thls is moving along. In this case, the supporting means 1 does not consist of an endles~s driven belt but of endless ropes passed over said both rolls 5, which provides .

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the possibility that any excess of the aqueous dispersion of synthetic plastics material can flow off.
There is conveniently used a liquid solution o~ a synthetic plastics material or an aqueous dispersion of synthetic plastics material containing more than 40 per-cent by volume of solid matter. It is of advantage if there is used a cross linking dispersion of polyurethane and/or polybutadiene substantially being not thermoplastic.
The lower roll 5 forms a deflection area for the belt 1, at which the split leather provided with the liquid dressing is lifted off the belt 1 and is placed on a supporting base 2 formed of a conveyor belt such that that side of the split leather 3 rests on this conveyor belt 2 which has been pro-vided with the liquid dressing 4. The conveyor belt 2 is moved with the same speed as the belt 1 so that when transferring the split leather 3 provided with the dressing onto the conveyor belt 2~no relatlve shifting movement between the split leather 3 and the conveyor belt 2 takes place.
A counter roll 7 supportlng the conveyor belt 2 is provided below the lower roll 5 for preventing sagging of the conveyor belt~2 wlthin the- transfer area. This con-veyor belt 2 is passed over rolls~8.
Peeling of the split leather 3 provided with the dressing 4 from the conveyor belt ~ and transfer of this split leather onto the conveyor belt 2 can be facilitated if a pressurized air nozzle 19 is arranged at the transfer ....
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area and the pressurized air flowing out of this nozzle is flowing against the split leather 3 and loosens it from the belt 1.
The conveyor belt 2 preferably consists of silicone rubber, noting that the top surface of the conveyor belt 2 has a negative grain structure, so that the dressing soli-difying on the conveyor belt 2 is provided with a grain structure and thus has an appearance similar to that of leather. For accelerating film formation of the dressing, the conveyor belt 2 is heated by heating means, for example by infrared radiators 19'. Heating can, however, also be effected, for example, by means of a gas-fired radiator.
Such heating reliably provides for a more rapid removal of the water or solvent, respectively.
The embodiment according to Figure 2 differs from the embodiment according to Figure 1 by the fact that, in place of the conveyor belt 2, a supporting base 2' is provided which is formed of a plate-like carrier body and is moved in ~orward direction over transport rollers 9. The plate--like carrier body preferably consists of silicone rubber and is provided with a reinforcing insert formed of a fleece or fabric of glas flbres, asbestos fibres or carbon fibres.
These materials have the advantage of a low weight and of nearly no heat expansion and of being resistent, like the silicone itself, to the existing temperatures.
The reinforcing insert can be embedded within the supporting base 2', but can also be provided at the lower ''' `' `` ', :' , , -` 129~9~59~

side of the supporting base.
The supporting base 2' can also-be constructed of two layers, the upper layer showing the surface structure being softer and more elastic, respectively, than the lower layer.
Furthermore, a transfer roll 10 is provided at the transfer area for transferring the split leather 3 provided with the dressing 4 to the plate-like carrier body 2'. Also this plate-like carrier body 2' is heated by heating means 19', for example infrared radiators.
The use of a plate-like carrier body 2' as the supporting base has the advantage that the dressed leather can, together with the carrier body 2', be transported away for further processing as will be explained later in detail.
In place of the transfer roll 10 there can also be provided a transfer belt by means of which the orientation of the split leather can be changed during transfer onto the plate-like carrier body 2'.
The plate-like carrier body 2'~itself can have a negative leather grain structure, so that the dressing soli-difying on this carrier body is given a grain structure on its surface, but it is also possible to place onto the plate--like carrier body a paper sheet coated with synthetic plastics material and having a structured surface and causing the formation of a structured surface of the dressing. Of course, a paper sheet having such a structured surface can also be placed onto the conveyor belt 2 (Figure 1), now 129~S9~

having no negative leather grain structure, for forming the leather grain structure of the dressing, said paper sheet consisting, for example, of an endless paper band to be drawn off a storage roll.
In the embodiment according to Figure 3~there are provided pressing rolls or, respectively, compressing rolls 11, 11' by means of which the split leather 3 provided with the dressing 4 being in the solidifying stage is pressed against the top surfacej being provided with the grain structure, of the conveyor belt 2. From Figure 3 can further be derived that the conveyor belt 2 need not extend within a plane over its whole length, but can be deflected for a certain angle at the area of the counter roll 7 as this i5 shown in Figure 3 by dashed lines. Such an arrange-ment facilitates transfer of the split leather 3 provided with the dressing 4 from the belt 1 onto the conveyor belt 2.
Also in the embodiments according to the Figures 2 and 3 pressurized air nozzIes 19 can be provided for loosening the split leather.
Figure 4 shows the appllcation of a layer ~2 onto the conveyor belt 2, which is necessary for a dressing comprising two layers. Of course, such a layer can also be applied onto a plate-llke carrier body 2'~forming the supporting base or, respectively, onto the paper~sheet. Formlng the dressing of two-layers~ of which the inner layer located adjacent the split leather 3 is preferably of greater thck-ness than the outer~layer having the structured surface, 5~

provides the advantage that the dressing has better abrasion resistance than a dressing formed of one single layer.
Application of an aqueous dispersion or liquid solution of synthetic plastics material forming the layer onto the conveyor belt 2 or, respectively, onto the carrier body 2' is effected, for example,by pouring or spraying a thin layer by means of a suitable device 20 onto the supporting base 2 or 2', respectively, heated to a temperatures of more than 70 C. Thereby, micropores are formed in the desired manner, because solidification of the poured or sprayed dispersion already starts on impingement onto the heated supporting base.
If the supporting base consists of a paper sheet pro-vided with a structured;surface, it is of advantage to applythe aqueous dlspersion or, respectively, the liquid solution of synthetic plastics material onto the paper sheet by means of a wiper.
Conveniently, the aqueous dispersion of synthetic plastics material applied onto the supportlng base by pouring or spraying and formlng the outer layer has a lower viscosity and the liquid solution of synthetic plastics material appIied to the supporting base by wiping has a higher viscosity than the dispersion applied onto the ~leather 3 and~forming the inner layer 4 embedding the fibres.
Placing of the split leather 3 provided with the still \ wet layer 4 onto the supporting base 2 or 2' i9 only effected lZ~4~

if the layer 12 has already become solidified at least to a substantial degree. For fulfilling this condition, the application device 20 for applying the layer 12 onto the supporting base 2 or, respectively, 2' is located at a distance from the transfer area for transferring the leather 3~from the conveyor belt 1 to the supporting base 2 or, respectively, 2' at one side of this transfer area.
The speed of the belt 1 and of the supporting base 2 or, respectively, 2' is conveniently infinitely variable to be in the position to adapt this speed to the existing requirements. The preferred speed for advancing the split leather 3 is between 3 and 8 m/min.
The described construction of the apparatus provides, in particular, the advantage that adhesion of the dressing compound 4 on the leather 3 is improved on account of directly or, respectively, immediately applying onto the leather 3 the dressing being in the liquid phase, so that the fibres protruding from the leather are embedded within the dressing and the dressing is inseparably bonded to the ~0 leather. On account of no manually turning over of the leather provided with the wet dressing being necessary, the finished dressing has no disturbing defects which result from grasping the leather provided with the dressing still wet or from subsequent shifting the leather having already been turned over and placed on the support. By using this apparatus, the time interval passing between application of the liquid dressing and placing the leather provided with the liquid , ~ 9~54 dressin~ is reduced and can, above all, exactly be pre-determined. Thus, the supporting base 2 or 2', respectively, can more intensely be heated and drying of the dressing takes place within a shorter time. Furthermore, there is pro-vided the possibility to apply the dressing compound ontothe leather as a layer of smaller thickness, because, on account of the possibility to make very short the time interval passing between applying the liquid dressing and turning over the leather and placing same onto the supporting base 2 or 2', it is made sure that substantially no liquid evaporates or migrates into the leather.
The use of the apparatus further provides the possibili-ty to firmly and inseparably bond to the split leather 3 also porous, air-permeable and steam-permeable dressings having a density of less than 0.8 and being particular-ly suitable for the production of shoe uppers to be pro-vided with a polyurethane sole by foaming same onto the upper, because the shoe upper consisting of the inventive split leather allows, when being inserted into the mould required for forming the polyurethane sole, escape of the air during foaming operation on account of being porous.
Furthermore, the polyurethane sole is excellently mechani-cally anchored to the shoe upper during the foaming operation, because the polyurethane penetrates into the porous dressing, so that an excellent bond between the dressed split leather and ~he polyurethane sole is reliably obtained.

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To provide for ease of cleaning o$ the component parts of the apparatus, all components coming into contact with the liquid solution or, respectively, the aqueous dis-persion of synthetic plastics material, for example the rolls 10, 11, are provided with a coating of a silicone varnish or of silicone rubber.
Figure 7 shows an apparatus according to the invention in a top plan view~according to which the supporting means con-siSts of an arcuate deflecting device formed of a plurality of transport rolls 1'. In this apparatus there is used a known device for applying the dressing, being in the liquid phase, onto the split leather, said device consisting of a conveyor belt 18,on which the split leather is advanced, noting that the dressing is uniformely applied onto the split leather via the application roll 6. At the end of the conveyor belt 18;which is located opposite the application roll 6, there are arranged~the transport rolls 1, being at least in part driven and.being arranged such that the split leather 3 is deflected for approximately 90 by these trans-port rolls 1' receiving the-split leather from the conveyor belt 18. The last of said transport rolls 1' forms the deflection area 5,at which the s.plit leather having applied thereon the llquid dressing 4 is placed on the supporting base formed of a conveyor belt 2 such that that side of the split leather rests on this conveyor belt 2 which has been provided w1th the.l1quid dressing 4. Of course, also in this embodiment there can be provided, in place of the conveyor .....

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belt 2, a supporting base 2' formed of a plate-like carrier body and being advanced via transport rolls in an analogous manner as in the embodiment according to Figure 2. In any case, the deflecting device has as an effect that the trans-port belt 2 or, respectively, the supporting base 2' advancedvia the transport rolls can be arranged at a position~in which the device for applying the dressing onto the split leather forms no obstacle.
Figure 8 schematically shows the continuous sequence of working steps when dressing a split leather. The supporting bases 2' of silicone rubber are advanced in direction of the arrow 22 on a conveyor belt 21 replacing the transport rolls 9 in Figure 2. The top surface of the supporting bases 2' is a structured surface. An aqueous dispersion or a liquid solution of synthetic plastics material is poured or sprayed onto this top surface and is allowed to solidify during further advancement, solidification being accelerated by heating means (not shown) heating the supporting bases 2'.
At a distance from the device 20, there is located the ~0 transport band 1~on which the split leather 3 is resting.
An aqueous dispersion of synthetic plastics material is applied onto the split leather in the described manner via the application roll 6 and subsequently the split leather is, with its wet side facIng downwardly, placed onto a supporting base 2' havlng been provided, as explained above, with an already solidified layer.
The thus dressed split leather is deflected via trans-- . . ~

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port rollers 2~' and arrives on a further conveyor belt 23 where the dressed split leather i5 pressed against the supporting base 2 7 by means of press rolls 11. After a further deflection via transport rolls 23', the dressed split leather enters a vacuum device 24 to be later described in detail and moves from there via transport rolls 25' onto the conveyor belt 25 where at 26 the finished spli.t leather 3 now provided with a dressing is removed. The supporting bases 2' are further advanced and return again onto the conveyor belt 21 via transport rolls 27'.
The Figures 9 and 10 show a first embodiment of a vacuum device. Tables 29 forming a carrier body for the supporting base 2' are fixed on a rotatable carrier member 28 which is rotatable around an axis 28'. At the location 33, a table 29 is charged with a supporting base 2' carrying a dressed split leather. Subsequently the tables 29 are moved in direction of the arrow 34. At the following location, there is placed onto the table 29 a diaphragm 30, which can be rectangular, in particular of s~uare shape, but can also be of round, in particular circulax, shape and which has at its edge a packing strip 31 extending around the circumference and havlng its free end, which is preferable provided with a profile, restlng on the table 29. The dia-phragm 30 pxovided with the packing stri.ps 31 thus encloses the supporting base 2' together with the split leather 3.
An opening 32 arranged at a location of the packing strips and provided with a valve can be connected with a ~L2g~4S~.

vacuum source (not shown), so that, after having connected this vacuum source, a reduced pressure is generated within the space enclosed by the diaphragm 30 and the packing strip 31 and provokes that the diaphragm 30 engages the split leather 3 and presses this split leather against the supporting base 2', noting that simultaneously the vapors generated on drying the dressing are sucked off.
The diaphragm 30 as well as the packing strip 3 consist of an elastomeric material, the packing strip 3~
being preferably formed of a softer material than the dia-phragm 30. The elastomeric material in question is preferably caoutchouc or, respectively rubber, in particular silicone rubber.
If the valve of the opening 32 is being closed, the reduced pressure is maintained even when interrupting the connection with the vacuum source. Subsequently, the table 29 is, together with the supporting base 2' and the diaphragm 30 pressed against the split leather 3, brought into the position shown at the right hand of Figure :9 and finally arrives at the discharge location 35 where the valve of the opening 32 is opened, so that the.space enclosed by the diaphragm 30 and the packing strips 31 is connected with the atmosphere. On account of-the restoring force intrinsic for the materlal of the dlaphra~m, the diaphragm 30 again returns in its starting position and can be lIfted off, whereupon the dressed split.leather is removed togeth.er with the supporting base 2'.

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In the embodiment according to the Figures 11 and 12 t~ere is provided a carrier body consisting of plate members being, via protruding extensions 37, in connection with conveyor chains 38 passed over sprocket wheels 39. In place of the plate members, also lamellae or tubular carrier bodies may be provided.
The supporting bases 2' carrying the split leather 3 provided with the dressing rest on the plate member 36. The supporting bases 2' are conveniently arranged such that they cover each one gap between two adjacent plate members 36.
Below the plate member 36, there are located heating means, for example infrared radiators 40,by means of which the Flate member 36 and therewith also the bases members 2' are heated.
The plate member 36 cooperate~with a diaphragm 41 con-sisting of an endless band being passed over rolls 42. This :
diaphragm 41 formed of the endless~band lS designed such that a tight closure between the-diaphragm and the support-ing bases 2' or, respectively, the plate member 36 lS
possible, so that here again a sub-atmospheric pressure can be produced within the interstice. For this purpose, packing strips 43 of an elastomeric-materiaI are, in the embodiment shown in Figure 11, provided at the marginal areas, extending ln~advancing direction,~of the diaphragm 41, and optionally packing strips 44 transversely extending to the advancing direction are also provided. It has, how-ever, been found that a vacuum can be generated also without , ~

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providing such packing strips. ~ithin the packing strips or within the diaphragm 41 (if packing strips are omitted) there are again provided openings 45 equipped,wi~h a valve and adapted to be connected with a vacuum source. This again results in pressing the diaphragm 41 against the split leather 3 located on the supporting base 2' as well as in sucking off the vapors generated on drying the dressing.
The endless band forming the diaphragm 41 is of shorter length than the carrier body formed of the plate member 36 and acting like an endless band , so that the finished dressed split leather 3 can in a simple manner be discharged together with the supporting base 2'.
Sucking off of the vapors is improved if grooves 41a are provided at the side of the diaphragm 41 facing the leather, via which grooves the vapors formed can escape.
Of course, such grooves can also be provided in the diaphragm 30 of Figures 9 and 10.
The plate members 36 preferably consist of metal, for example steel. The arrangement of individual plate members in place of an endless steel band results in the advantage that any heat expansion of the plate members is, on account of the resulting sub-divls1on, not disturbing. In particular when using supporting bases,2' of a silicone, the gap between adjacent plate members 36 is sealed by these support-ing bases such that this gap does not prevent the generationof a vacuum. This vacuum is, in this case, generated between the supporting base,2' of silicon rubber and the diaphragm 41 :, . .

, and the packing strips 43, 44 (if present), noting that the diaphragm 41 is subdivided into a plurality of chambers by the packing strips 44.
The diaphragm 41 formed of an endless band conveniently consists of rubber orcaoutchouc and can be reinforced by a metal mesh, a fabric or a fleece. The reinforcement can either be arranged as an insert within the diaphragm or be placed onto the outer side of the diaphragm.
As a rule, the weight of the diaphragm 41 proper is sufficient to establish an initial seal relative to the supporting base 2', said seal being the premise for the following generation of the vacuum. However, also press rolls 42' can be provided for pressing the diaphragm 41 against the supporting base 2'. Furthermore, also the diaphragm 41 is conveniently heated by heating means 40' , for example infrared radiators, which results~in the advantage that any residues of the still liquid solution or still aqueous dis-persion of the synthetic plastics material adher~ing to the diaphragm become there solidified and can subsequently easily be removed from the dlaphragm.
The packing strips 43, 44 conveniently consist of a softer material than the diaphragm 41 and are glued or vulcanized to~the diaphragm 41.
If the plate members 36 are not of metal but conslst of a heat resistent synthetic plastics material, it is possible to arrange the packing strips on these plate members inctead un th~ dlaphragm.

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The diaphxagm 41 can also be arranged on an endless steel band.
In the embodiment according to Figure 13, the carrier body consists of an endless band 46 of steel or of an elasto-meric, heat-resistent material, said band being supported by supporting -rolls 47. Furthermore, heating means 40 are also in this case provided.
The band 46 carries a paper sheet 48 having already applied on its structured top surface a coating formed of an aqueous dispersion or of a liquid solution of synthetic pla-stics material, said coating forming the outer layer of the dressing. This paper sheet 48 replaces the supporting base 2'.
Onto this paper sheet 48, there is placed in the described manner the split leather 3, having thereon the still aqueous dispersion of the synthetic-plastics material, such that the wet side contacts the paper sheet. A diaphragm 49 comprising packing strips 50 extending around the circ~mference is placed on each split leather 3 having been placed onto the paper sheet.
Here again, each diaphragm 49 has an opening 51 equipped with a valve and being adapted to be connected to a vacuum source.
By applying;the vacuum, the diaphragm is again pressed a~ainst the split leather and the vapors are sucked off. The split leather is, together with the diaphragm, further advanced by the band 46. At the end of this band, the diaphragm is li~ted and the dressed split leather is peeled from the paper sheet 48. The layer having been prefabricated on the paper sheet 48 then forms the outer layer, containing the~plgment, of the dressing.

3 2~45~ -The paper sheet can again be provided with such a layer and can then again be used.
The band 46 is passed over rolls 52.
Also in this case, grooves 41a are conveniently again provided at the side of the diaphragm 49 facing the split leather 3 for facilitating removal of the vapors.
The operating steps of all described vacuum devices can be controlled to be in conformity with the speed of the pre-ceding devices/so that a continuous production is possible.
In all apparatuses, the diaphragms may consist of various products of elastomeric properties such as natural rubber, synthetic rubber, silicone rubber and elastic poly-urethane.
The Figures 5 and 6 show a dressed split leather in an enlarged scale. In the embodiment according to Figure 5, the split leather 13 is provided on its one side with a mono-laYer dressing 14 having been formed of an aqueous dispersion of synthetic plastics material and having embedded therein hollow microspheres. As can be seen, the fibres completely extend into the dressing 14 at the top surface of the split leather 13 facing the dressing 14, which results in an inti-mate bond hetween the spllt leather 13 and the dressing 14.
The v1sible side 16 of the dressing 14 is given a structured surface and thus has, ~or example, an appearance similar to ~5 that of leather.
In the embodiment according to Figure 6, the dressing consiFts of two layers~14a, ~4b, thë inner layer completely 12~54 receiving the fibres of the split leather ~3 having em-bedded therein hollow microspheres 14a. This inner layer 14a has preferably a neutral color and contains neither pigments nor dye stuffs.
The outer layer 14b has a substantially smaller thickness than the inner layer 14a and comprises no hollow microspheres but instead therefor such an amount of pigments or, re-spectively,dye stuffs,that the tinge of the dressing is defined. The top surface 16 of this outer layer 14b is again given a structured surface and thus has an appearance similar to that of leather.
If the inner layer 14a located adjacent the leather has a neutral tinge relative to the leather and relative to the outer layer 14b and if pigments and/or dye stuffs are incorporated only in the outer layer 14b for defining the color of the dressing, there resul.ts the advantage that, in case a change in color of the dressing shall be effected, only the aqueous dispersion or liquid~solution of synthetic plastics material forming the outer layer 14b must be re-placed by an other one or, respectively, the applicationmeans therefor must be interchanged. In this case it is not necessary to adapt the color of the dispersion of syn-thetic plastics material forming the inner layer 14a and having a milky appearance. The neutral color of the inner layer 14a makes further sure;that any inking of the leather to be provided with the dressing becomes not visible on the top surface of the dressing even if strongly inked leather is used.
It is of particular advantage if the inner layer ~4a has a pore structure or foam structure, respectively. Such a layer has then the desired permeability for steam or water vapor. This further favourizes design of this inner layer in a neutral manner with respect to color. The pore structure or foam structure, respectively, can in particular be achieved if hollow microspheres having a diameter of 0.008 to 0.10 mm and having a thin shell of thermoplastic material, preferably of a vinylidenchloride copolymer, are embedded at least into the inner layer. Such hollow microspheres are known per se.
Optimum results are obtained if the inner layer comprises more than 8 percent by volume of hollow microspheres.
For optimum results, also the density of the layers is of importance. Conveniently,-the inner layer has a density between 0.6 and 0.8 and the outer layer has a density between 0.82 and 1.24.
Furthermore, a reinforcing:insert formed, for example~
of a textile material or of-a -fleece material having a weight per unit area of less than 80 g/m2 can be arranged within at least one layer. The permeability of the dressing for water vapor can be increased in the desired manner by this reinforcing insert. Furthermore, such an insert acts like an armoring and prevents excessive elongation and thus destruction of the dressing on tension stress.
If the structured surface of the outer layer shall be given a special appearance, an additional thin finish layer~

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for example a layer influencing the lustre or the color, can be arranged on this surface. This additional layer does, however, not form a necessary component of the dressing which is, as already mentioned, conveniently formed of two layers. The thickness of this additional layer having been applied only at a later stage is thus not to be considered in the thickness of the dressing.
The structured surface of the dressing can, as is desired, have the appearance similar to that of leather grain or have the appearance of a finely ground leather of fully--grained type, the latter-resùlting in a pile effect.
The split leather has, in combination with the dressing~
conveniently a permeability for water vapor of more than 0.3 mg/cm . The permeability for water vapor is measured according to JUP 15, an European Test Specification for determlning the permeability of leather for water vapor.
For forming the dressing, an aqueous dispersion of synthetic plastics material is applied, in the~wet stage, in an amount between 150 g/m2 and 450 g/m2 and preferably in an amount of approximately 300 g/m2, whereupon the leather is, with its side provided with the dressing facing downward, placed onto a supportlng base having a structured surface and finally the leather with the dispersion of synthetic plastics material applied thereon is compressed and subjected to a vacuum treatment. When applying the dlspersion of synthetic plastics material in the indicated amount, ~here is produced a dr_ssing of such a thickness ... .

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that, on the one handla good and inseparable bond with the leather is obtained and fibres protruding from the leather are completely embedded in a reliable manner and that, on the other hand, the properties of the leather are not ad-5 versely influenced by the dressing. On account of the leatherbeing placed on the supporting base having the structured surface with its side carrying the dressing facing down-wardly, the structure in the dressing is produced immediate-ly on solidification of the dressing, so that no separate operating step is required thereforj noting that a bubble--free solidification of the dressing with simultaneous formation of the structured surface is assisted by the pressing step and by the vacuum treatment.
For imparting to the layer located adjacent the leather and completely receiving the fibres protruding from the leather the desired foam structure, there are conveniently incorporated into the aqueous dispersion of synthetic plastics material and prior to applying same hollow micro-spheres having a diameter of 0.008 to 0.1 mm, the thin shell of these microspheres consisting of thermoplastic material, preferably of a vinylidenechlorlde copolymer.
If the dressing is formed of two layers, a further aqueous dispersion of synthetic plastics material or a further liquid solution of synthetic plastics material is applied onto the structured surface of the supporting base prior to placing the leather having applied thereon an aqueous dispersion of synthetic plastics material onto said - l~g~54 supporting base, noting that the leather is placed onto the supporting base only after solidification of said further aqueous dispersion or, respectively, liquid solution of synthetic plastics material. This further aqueous dispersion or, respectively, liquid solution of synthetic plastics material may then, for example directly form a finish.
Example 1:
A split leather dressed according to the invention and being comparable with respect to its appearance and its pro-perties with a full-grained natural leather of the same type and thickness is produced in the following manner:
A support base of silicone being reinforced by an asbestos fabric insert and being composed of two layers is placed onto a moving belt and heated on this moving belt during further advancement to approximately 85 C by means of infrared radiation. The supporting base consisting of silicone has a size of 2.4 m2 and a thickness of about 3 mm.
An aqueous dispersion containing about 45 percent solid matter is applied by pouring onto the supporting base of silicone having a temperature of about 45 C. The dispersion contains about 40 percent-polyurethane and about 5 percent white pigment and has a viscosity of approximately 60 seconds (the viscosity is determined in the Ford-beaker using a 4 mm nozzle). The wet dispersion is applied onto the warm supporting base in a thickness of approximately 0.11 mm, thickening and subsequent solidification of this dispersion taking place immediately after arrival on the supporting base g54 by evaporation of water. The supporting base has a structured top surface, so that on solidification of this layer com-prising the pigment/there is simu-ltaneously formed the later visible grain structure of the dressing. The solidified outer layer has a thickness Ot- approximately 0.6 mm. The polyurethane dispersion forms a film having a hardness of approximately 90 Shore A.
During solidification, the svpporting base is moved on the conveyor belt with a speed of 4.5 m~min. 8 meters behind the pouring station for the dispersion containing the pigment, there is placed on the pre-dried and pigment-con-taining layer on the supporting base - without manual assistance - a split leather, onto which previously has been applied an aqueous dispersion of synthetic plastics material, with its wet side. The spli-t leather has a size of approxi-mately 1.3 m2 and a thlcknes~s of 1.4 mm and has a light chrome green color.
The dispersion applied to the split leather is a poly-urethane dispersion containing approximately 62 percent solid matter. This solid matter i-s substantially composed of 50 percent polyurethane and 10 percent hollow microspheres as well as a thickening agent. The a~ueous dispers~on has :
a ViSCoslty of approximately 280 seconds (as measured in a Ford-beaker using a 4 mm nozz-le) and forms on drying a film having a hardness of approxlmately 65 Shore A and a density of approximately 0.78. Application of the relativeIy viscous dlspersion onto the split leàther has been effected by ~:

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means of a roll rotating in opposite direction to the direction of movement of the leather~so that the dispersion is, by making use of the shearing forces, massaged into the leather and substantially fills all interstices between the protruding fibres. On account of the fibres protruding from the leather having differing length, the thickness of the layer can not be determined. The applied weight of the wet dispersion was approximately 240 g/m2.
After having placed the leather onto the solidified pigment layer on the supporting base, this leather is pressed onto the supporting base by means of a soft, elastic roll coated with a silicone, so that air inclusions, if any, between the pigment layer and the wet dispersion of syn thetic plastics material-applied onto the leather can escape.
Subsequently,the leather provided with the dressing and resting on the supporting base is, together with the supporting base, introduced into a warm vacuum device being equipped with a diaphragm, noting that within the diaphragm a reduced pressure is produced,-so that the diaphragm is moved in downward direction and is pressed against the leather.
The diaphragm becomes thereby adapted to the contours and presses the leather onto the supporting base. The gases and the steam generated when heating the vacuum device are suc~ed of~ via the;vacuum condui-t. After approximately 75 seconds, the flnished dressed l-eather can ~e removed from the vacuum device.` During this time, the vacuum device has been further advanced/so that-the production is a continuous ., ' . :: .

129~5~-. - 31 -one.
Example 2:
A split leather provided with a grained dressing of particular high abrasion resistanGe ~s produced as follows:
A polyurethane solution of high viscosity is applied by means of a wiper or doctor blade., respectively, in a thickness of 0.13 mm onto a carrier consisting of paper and having a negative grain structure and a surface finish allowing release of a solidified polyurethane film. The polyurethane solution contains a-s solid matter substantially 38 percent of polyurethane and 3 percent of a brown pigment.
This solution forms on drying a film having a density of approximately 1.05 and a hardness of approximately 98 Shore A.
This pigment layer is prefabricated on the carrier consist-ing of~paper, so that this carrier can, together with apigmented layer, be stored until being used.
When producing the dressing of a split leather, the carrier of paper is placed on a supporting base, for example a conveyor belt, and moved ln direction to. the transfer location for the leather having been provided with the wet dispersion of synthetic plastics material, where the leather is - without manual assistance .--p-laced with its wet side onto the pigment layer of the carrier cons sting of paper.
: The aqueous dispersion of synthetic.plastics material applled to the~leather is free of pigments and has a milky appearance.
~ Subsequently, the paper sheet runs, with the leather , ~

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placed thereon, below and past the application device for applying the aqueous dispersion of synthetic plastics mat~rial onto the leather to a pair of rollers where pressing is effected.
The layer of aqueous dispersion applied to the leather corresponds with respect to its composition and amONnt to that in example 1.
Subsequently, the supporting base of paper is, together with the split leather placed thereon, received by a heated endless steel band having a.length of more than 12 m and a width of more than 1.2 m and further advanced by the steel band such that at those areas where the leather is placed on the paper sheet;. a rubber cover comprising a sealing frame and an opening, being equipped with a valve, for 15 . connecting thereto a vacuum force and acting as a diaphragm, is placed onto the leather in a position to cover the leather.
Subsequently, the air present within the rubber cover is sucked off, so that the diaphragm engages the leather and presses the leather onto the paper sheet or, respectively, the steel band under the action of the generated reduced pressure. Under the influence.of.the pressure exerted by the diaphragm on the leather~ there results a good bond between the~pi~gment layer applied.to the paper sheet and the dispersion layer comprising the hollow microspheres and embedding the flbres of th~e leath:er while the dispersion layer becomes solidified. Under the action o~ the reduced pressure and under the action of heat, the dispersion layer is rapidly d~.ied.
Heating of the stell band to a temperature ~etween 70 and 140 C is effected by expos.ing the lower side of the steel band to the radiation of infrared radiators.
Approximately 60 seconds after applying the vacuum, the valve is opened and the-rubber cover assumes,on account of its elastic properties, its ori-ginal shape. After having removed the rubber cover, the finished leather can be peeled from the paper sheet. By longitudinal grooves and transverse grooves provided in the rubber cover it is made sure that gases and water vapor can:escape.from the leather even if the diaphragm is pressed against the leather under the action of the vacuum.

Claims

1. A split leather provided with a dressing which consists of two layers connected with each other, said layers comprising an inner, substantially non-thermo-plastic layer immediately neighbouring the split leather and completely absorbing fibers protruding from the split leather, this inner layer being made of an aqueous dispersion of cross-linkable synthetic plastics material and having a porous or foamy structure, this inner layer together with the embedded fibers having a density below lg/cm3, and an outer layer connected to the inner layer and being made of a liquid cross-linkable synthetic plastics material containing polyurethane, said outer layer having on its outer side a textured surface and having a greater density and hardness than the inner layer.

2. A split leather as claimed in claim 1, wherein the outer layer comprising the texture surface is formed from an aqueous dispersion comprising polyurethane.

3. A split leather as claimed in claim 1, wherein the outer layer comprising a textured surface is formed from a liquid solution comprising polyurethane.

4. A split leather as claimed in claim 2, wherein the inner layer located adjacent the leather is made neutral with respect to color relative to the leather and relative to the outer layer comprising the textured surface and wherein pigments or, respectively, dye stuffs are incorporated into the outer layer and define the color shade of the dressing.

5. A split leather as claimed in claim 1, wherein the inner layer has a hardness of approximately 65 Shore A.

6. A split leather as claimed in claim 1, wherein the outer layer has a hardness of approximately 90 Shore A.

7. A split leather as claimed in claim 1, wherein the inner layer has a density between 0,6 and 0,8.

8. A split leather as claimed in claim 1, wherein the outer layer has a density between 0,82 and 1.24.

9. A split leather as claimed in claim 1, wherein the thickness of the inner layer is greater than 0,11 mm.

10. A split leather as claimed in claim 9, wherein the thickness of the inner layer is greater than 0,21 mm.

11. A split leather as claimed in claim 1, wherein the thickness of the outer layer is smaller than 0,16 mm.

12. A split leather as claimed in claim 11, wherein the thickness of the outer layer is smaller than 0,10 mm.

13. A split leather as claimed in claim 1, wherein hollow microspheres having a diameter between 0.008 and 0.10 mm are embedded at least in the inner layer, the thin shell of the microspheres consisting of thermoplastic material.

14. A split leather as claimed in claim 13, wherein the thin shell of the hollow microspheres consists of a vinylidenechloride copolymer.

15. A split leather as claimed in claim 13, wherein the inner layer contains more than 8 percent by volume of hollow microspheres.

16. A split leather as claimed in claim 1, wherein at least one layer is provided with a reinforcement.

17. A split leather as claimed in claim 18, wherein the reinforcement consists of a textile material having a weight per unit area of less than 80 g/m2

18. A split leather as claimed in claim 16, wherein the reinforcement consists of a non-woven fabric having a weight per unit area of less than 80 g/m2.

19. A split leather as claimed in claim 1, wherein the structured surface of the outer layer is provided with an additional thin finish layer.

20. A split leather as claimed in claim 1, wherein the structured surface of the outer layer has an appearance similar to that of leather grain.

21. A split leather as claimed in claim 1, wherein the structured surface of the outer layer has the appearance of a finely ground full-grain leather.

22. A split leather as claimed in claim 1, wherein at least the outer layer contains finest cellulose particles.

23. A split leather as claimed in claim 1, wherein at least the outer layer contains heat-sensible substances.

24. A split leather as claimed in claim 23, wherein at least the outer layer contains polyvinylmethylether.

25. A split leather as claimed in claim 1, wherein it has, together with the dressing, a permeability for water vapor of more than 0,3 mg/cm2.

26. Process for dressing of split leather, comprising the steps: applying a liquid cross-linkable synthetics plastics material containing polyurethane onto a textured surface of a supporting base and heating the supporting base for at least partially solidifying said liquid synthetic plastics material, so that an outer layer of the dressing is formed, applying a cross-linkable aqueous dispersion, which dispersion forms after solidification a substantially non-thermoplastic inner layer of the dressing, onto the leather by means of a rotatable application roller along which the leather is moved, keeping a relative velocity between the rotational movement of the application roller and the moving leather so that the aqueous dispersion is massaged into the leather, wherein the quantity of the applied dispersion is so chosen that the fibers protruding from the split leather are completely surrounded by the inner layer, subsequently placing the aqueous dispersion in the wet stage together with the leather on which said dispersion is applied, onto the said at least partially solidified outer layer supported on the textured surface of the supporting base;
subsequently drying the aqueous dispersion forming the inner layer during its staying time on the supporting base heating same from its lower side, moving off during this time the vapor generated during drying at least partially through the split leather;
subsequently abutting the split leather together with the dressing consisting of the outer layer and the inner layer onto the supporting base and subjecting it to a pressing operation;
and lastly taking off the dressed split leather from the supporting base.

27. The process of claim 26, wherein the step of heating the supporting base is carried out before the step of applying the liquid cross-linkable synthetics plastics material onto the textured surface.

28. The process of claim 26, wherein the step of heating the supporting base is carried out after the step of applying the liquid cross-linkable synthetics plastics material onto the textured surface.

29. The process of claim 26, wherein the step of heating the supporting base is carried out during the step of applying the liquid cross-linkable synthetics plastics material onto the textured surface.

30. Process as claimed in one of claims 27, 28 and 29, wherein the viscosity of the cross-linkable aqueous dispersion forming the inner layer is greater than the viscosity of the liquid synthetic plastics material forming the outer layer.

31. Process as claimed in one of claims 27, 28 and 29, wherein for forming the inner layer a cross-linkable aqueous dispersion containing polyurethane is used in an amount between 150 g/m2 and 450 g/m2 in the wet stage.

32. Process as claimed in one of claims 27, 28 and 29, wherein for forming the inner layer a cross-linkable aqueous dispersion containing polyurethane is used in an amount between 150 g/m2 and 450 g/m2 in the wet stage, wherein for forming the inner layer a cross-linkable aqueous dispersion containing polyurethane is used in a amount of approximately 300 g/m2 in the wet stage.

33. Process as claimed in one of claims 27, 28 and 29, wherein the split leather together with the dressing formed by the inner layer and the outer layer is subjected to a vacuum treatment.

34. Process as claimed in one of claims 27, 28 and 29, wherein the split leather before applying the aqueous dispersion forming the inner layer is based on a further support and after applying the aqueous dispersion forming the inner layer the split leather together with the further support is turned over and laid onto the at least partially solidified outer layer.

35. Process as claimed in one of claims 27, 28 and 29, wherein the split leather before applying the aqueous dispersion forming the inner layer is based on a further support and after applying the aqueous dispersion forming the inner layer the split leather together with the further support is turned over and laid onto the at least partially solidified outer layer, and wherein paper is used as said further support.

36. Process as claimed in one of claims 27, 28 and 29, wherein the supporting base is moved during applying the liquid synthetic plastics material forming the outer layer.

37. Process as claimed in one of claims 27, 28 and 29, wherein the supporting base is moved during the split leather provided with the dressing is subjected to the pressing operation.

38. Process as claimed in one of claims 27, 28 and 29, wherein the supporting base is moved during the split leather provided with the dressing is subjected to the vacuum treatment.

39. Process as claimed in one of claims 27, 28 and 29, wherein the supporting base is abutted on a metallic carrier body which is heated at least for a time.

40. Process as claimed in one of claims 27, 28 and 29, wherein hollow microspheres having a diameter between 0.008 mm and 0.1 mm are added to the cross-linkable aqueous dispersion forming the inner layer before said dispersion is applied to the split leather, the thin shell of said microspheres consisting of thermoplastic material.

41. Process as claimed in one of claims 27, 28 and 29, wherein a cross-linkable aqueous dispersion forming the inner layer is used, which contains solid matter in a proportion of more than 40 percent by volume.

42. Process as claimed in one of claims 27, 28 and 29, wherein a cross-linkable aqueous dispersion forming the inner layer is used, which contains pigments or dye stuffs.

43. Process as claimed in one of claims 27, 28 and 29, wherein the liquid cross-linkable synthetic plastics material forming the outer layer is sprayed onto the supporting base.

44. Process as claimed in one of claims 27, 28 and 29, wherein the liquid cross-linkable plastics material forming the outer layer is poured onto the supporting base.

45. Process as claimed in one of claims 27, 28 and 29, wherein the liquid cross-linkable synthetic plastics material forming the outer layer is applied onto the supporting base by means of a wiper.

46. Process as claimed in one of claims 27, 28 and 29, wherein the direction of the rotating movement of the application roll is directed opposite to the direction of movement of the split leather.

47. Process as claimed in one of claims 27, 28 and 29, wherein the liquid cross-linkable synthetic plastics material forming the outer layer is applied to the already heated support base during movement said support base to that position in which the split leather provided with the applied aqueous dispersion forming the inner layer is put on, further heating said support base during this movement.

48. Process as claimed in one of claims 27, 28 and 29, wherein the supporting base used is a pre-fabricated paper sheet being provided with a film formed by solidification of a liquid synthetic plastics material.