CA1289228C - Liquid crystal display device - Google Patents
Liquid crystal display deviceInfo
- Publication number
- CA1289228C CA1289228C CA000548326A CA548326A CA1289228C CA 1289228 C CA1289228 C CA 1289228C CA 000548326 A CA000548326 A CA 000548326A CA 548326 A CA548326 A CA 548326A CA 1289228 C CA1289228 C CA 1289228C
- Authority
- CA
- Canada
- Prior art keywords
- angle
- liquid crystal
- polarizers
- cell according
- plates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
- G02F1/139—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering based on orientation effects in which the liquid crystal remains transparent
- G02F1/1396—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering based on orientation effects in which the liquid crystal remains transparent the liquid crystal being selectively controlled between a twisted state and a non-twisted state, e.g. TN-LC cell
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
- G02F1/133531—Polarisers characterised by the arrangement of polariser or analyser axes
Abstract
Abstract A liquid crystal display (LCD) cell comprising a twist nematic liquid crystal disposed between two electrode plates and polarizers and having a positive dielectric anisotropy.
The optical path difference .DELTA.n.d is 0.2 to 0.7 µm. The absolute value of the twist angle .PHI. can be between 10° and 80°, the angle ? between the polarizers can be between 80°
and 110° and the angle .THETA. between the surface orientation direction and the polarization direction on the screen on the light incidence side can be between -10° and 60°, preferably so that the polarizers are symme- trical of the nematic directors.
The optical path difference .DELTA.n.d is 0.2 to 0.7 µm. The absolute value of the twist angle .PHI. can be between 10° and 80°, the angle ? between the polarizers can be between 80°
and 110° and the angle .THETA. between the surface orientation direction and the polarization direction on the screen on the light incidence side can be between -10° and 60°, preferably so that the polarizers are symme- trical of the nematic directors.
Description
lZ~392%B
The invention relates to a liquid crystal display (LCD) cell comprising a twisted nematic liquid crystal layer which is disposed between two plates and polarizers having electrodes and surface orientations and which has a positive dielectric anisotropy.
The invention relates more particularly to an LCD cell of the kind set out wherein the nematic liquid crystal layer has a very low optical path difference.
If they are to have a high multiplex ratio, LCD cells must of course have a steep electro-optical characteristic.
The corresponding development was concentrated on highly twisted nematic structures. The term "highly twisted nematic structures" is to be understood as denoting structures having a twist of more than 90. Of course, doping with chiral additives is usually necessary to produce such a twist.
The advantages of liquid crystal cells having highly twisted nematic structures are a very steep electro-optical characteristic and a wide viewing angle range. The steep electro-optical characteristic leads to high multiplex ratios which are necessary to provide indications of high information density.
However, little regard was had for the fact that the main requirement for some purposes is not a high multiplex ratio but the possiblity of providing a highly differentia-ted grey scale. This is more particularly the case, for example, for television applications.
~u/10.8.87 It is therefore the object of the invention to provide an LCD cell having an electro-optical characteristic with a very low slope.
According to the invention, this object is achieved by an LCD cell of the kind hereinbefore mentioned which is characterized by the combination of: a twist angle ~ of from 10 to 80: an angle ~ between the surface orienta-tion direction and the polarization direction of the plate on the light incidence side of from -30 to 60: an angle ~ between the polarization directions of the two pola-rizers of from 80 to 110; and an optical path difference ~n.d of from 0.2 to 0.7 ~m.
In particular, the liquid crystal display (LCD) cell, according to one embodiment of the invention comprises a twisted nematic liquid crystal having a positive dielectric anisotropy which is disposed between two plates having electrodes and surface orientations.
The plates are disposed between two polarizers, and the LCD cell further includes, in combination, a twist angle 0 between the nematic directors of the liquid crystal at the respective plates of from about 10 to about 80; an angle e between the surface orientation direction and the polarization direction of the plate on the light incidence side of from about -30 to about 60; an angle between the polarization direction of the two polarizers of from about 80 to about 110: and an optical path difference ~n.d of from about 0.2 to about 0.7~m.
For the purposes of this description the following angles are to be understood as follows:
The twist angle ~ is the angle included between the planes which are defined by the two nematic directors on the 35 feont plate - i.e., the plate on the light incidence side -~ ,, ~28~2~8 2(a) and on the rear plate and which are perpendicular to theplates - i.e., in other words the angle by which the nematic directors are offset from one another. This definition corresponds to the conventional definition.
The angle ~ is the angle between the surface orienta-tion on the front plate or on the nematic director nl on the plate and the polarization direction of the polarizer associated with the last-mentioned plate. Positive values of the angle ~ indicate that the polarization direction is outside the angle ~ while negative values of ~ indicate a polarization direction between the nematic directors.
The angle ~ is the angle by which the polarizers are offset from one another. The polarizers are called crossed when they substantially bar the passage of light without any light-influencing means between them. This means that the term ~crossed~' covers all the corresponding values of and is not limited exclusively to a 9oo offset.
I'he resulting cell provides a positive contrast display and, surprisingly, is not coloured for low values of d~n and ~ = 0.
In positive contrast displays electrically energized 6egments appear dark on a bright background whereas in negative contra~t displays the situation is the converse.
Embodiments of the invention will be described herein-after with reference to the drawings wherein:
Figure 1 is a diagrammatic exploded view of an LCD cell ~5 according to the invention:
Figure 2 is a diagram showing the arrangement of angles, the 6urface orientations and the polarizers relatively to one another, and Figure 3 illustrates a voltage-contrast curve of a preferred embodiment.
The LCD cell according to the invention is of very similar construction to known cells, such as Twisted Nematic LCDs (Schadt and Helfrich, Appl. Phys. Lett. 18, 127 [1971~), so that there is no need here to go into construc-tional details. The cell according to the invention com-prises a liquid crystal layer 1 disposed between two plates 2,3 which are disposed substantially plane-parallel to one another and which are made of a transparent material such as glass or acrylic glass or plastic foils or the like. A
polarizer 4 is disposed before the front plate 2 and is preferably connected thereto, for example, by sticking. A
polarizer 5 is similar associated with the rear plate 3. The plates are separated from one another by a spacing or gap d.
~28922~3 On their surfaces facing the liguid crystal the plates 2,3 have conventional electrode coatings 6 segmented for the display of symbols or dots. Also, the surfaces are so treated as to exert a directional effect on the adjacent liquid crystal molecules and thus determine the direction of the nematic director n. The treatment resides, for example, in rubbing the surface in one direction or in the oblique evaporation of orienting layers etc; it is not necessary, but neither is it disadvantageous, to provide a tilt angle.
The result of this treatment will be called surface orienta-~ tion for the purpose hereof. An arrow 7 indicates thesurface orientation on the front plate 2. The surface orien-tation on the rear plate 3 is offset from that of the front plate and is indicated by an arrow 8.
The front plate polarizer is 80 disposed that its polarization direction includes relatively to the twist angle in the outwards direction a predetermined angle which will be described in greater detail hereinafter. The rear polarizer is so disposed that its direction of polarization Z crosses that of the first polarizer.
The liquid crystal 1 is a nematic liquid crystal which can have chiral additives.
Figure 2 illustrates the relative angular relationships of the nematic directors and the polarization directions. As previously stated, nl is the nematic director on the front plate 2 and n2 is the nematic director on the back plate ~. The angle of twist between the two nematic directors has the reference ~. This angle is approximately 50 in the present embodiment. However. it can vary on either side of 50. Satisfactory results are obtained with absolute values of ~ between 10 to 80, preferably 20 and 60, more particularly 30 and 50.
The front polarizer 4 has a polarization direction Pl.
In this embodiment such direction is offset by an angle of 20O from the nematic director nl. However, the direc-tion Pl can vary by an angle ~ from the nematic director nl in a range of from -30 < ~< 60. In other words, the polarizers can be arranged symmetrically of the nematic directors. The condition for this is ~ = (90-~)/2 if = 90. Symmetry is preferable but not obligatory. The polarization direction P2 f the rear polarizer 5 is offset from that of the front polarizer Pl by an angle ~
~ which is preferably 90. However, satisfactory results are obtained with an angle ~ of from 80 to 110. The polari-zation directions Pl and P2 can be changed over without adverse results.
~5 In other preferred embodiments, for example, ~ = 30O, ~ = 30 and ~ = 90, the following liquid crystal mixture (mixture "A") being used in a layer of a thickness d = 3.4 ~m:
Mixture "A"
ComPonent Concentration tweiaht ~) 0d(4)CP p-ttrans-4-(4-pentenyl) cyclohexyl]benzonitrile 8,000 5CP p-(trans-4-pentylcyclo-hexyl)benzonitrile11,000 4P(l)P p-(5-butyl-2-pyrimidinyl)-benzonitrile 3,000 35 sCAP02 P-t2-(trans-4-pentylcyclo-hexyl)ethyl~-ethoxybenzene 6,000 . .
:
128922~
3CEC3 trans-4-propylcyclohexane carboxylic acid-trans-4--propylcyclohexyl ester 8,000 4CEC4 trans-4-butylcyclohexane carboxylic acid-trans-4--butylcyclohexyl-ester11,000 5CEC3 trans-4-pentylcyclohexane carboxylic acid-trans-4--propylcyclohexyl-ester11,000 5CPAC4 1-t2-(trans-4-butylcyclo-hexyl)-ethyl]-4-(trans-4--pentylcyclohexyl)benzene 9,500 ~5 5CPPAC4 4-[2-(trans-4-butylcyclo-hexyl)-ethyl]4'-(trans-4--pentyl-cyclohexyl)biphenyl 5,500 20 sCPAPAC4 4-(trans-4-pentylcyclohexyl) -4'-t2-(trans-4-butylcyclo-hexyl)-ethyl]-l,l'-ethylene-diben~ene 7,000 25 4CEP02 trans-4-butylcyclohexane carboxylic acid-p-ethoxy--phenylester 11,000 5CEP01 trans-4-pentylcyclohexane carboxylic acid-p-methoxy-hexylester 9,000 A second example was prepared with the following mixture "B":
.
~ ' .
.
.
:
i289228 Mixture "B" Concentration ComPonent (weiaht %) 4Ptl)P p-(5-butyl-2-pyrimidinyl)-benzonitrile 8,8Z0 0d(3)CP p-~trans-4-(3-butenyl)-cyclohexyl]benzonitrile 7,390 L0 ld(3)CP p-~trans-4-(3E-pentenyl)-cyclohexyl]benzonitrile 7,4Zo 0dt4)CPP 4'-[trans-4-(4-pentenyl)-4-biphenylcarbonitrile 6,170 ~5 3CEC3 trans-4-propylcyclohexane carboxylic acid-trans-g-propylcyclohexyl ester 21,050 20 4CEC4 trans-4-butylcyclohexane carboxylic acid-trans-4-butylcyclohexylester 28,100 5CEC3 trans-4-pentylcyclohexane carboxylic acid-trans-4-propylcyclohexylester 21,050 The designation of the components is known to the skilled addressee. Reference is made in this connection, for example to the publication of Schadt, M. et al in Mol.
Cryst. Lig. Cryst. 122 (1985) 241ff and in Proc. Int. Displ.
Res. Conf., San Diego (1985).
The following Table 1 lists the relevant parameters of the two mixtures "A" and "B".
~289228 Table 1 Mixture "A" Mixture "B"
5 Clearing point TCl [C] 72 42.5 Melting point Tm [C] <-20 <o nO 1,432 1,476 Optical anisotropy ~n 0,086 0,072 Viscosity ~ 23 21 / (at 22C) ~m pa. s]
- The electro-optical results compiled in ~he following Table 2 were obtained with these mixtures. The results achieved with the novel cell according to the invention are in each case compared with the values obtained with the same liquid crystal mixtures in a conventional twisted nematic cell and listed in the third column.
Table 2 Mixture "A"
~=30 ~=60 ~=90 ~=30 ~=lS ~= 0 ~=so ~=so llr=90 Vlo (Volt) 2.165 2.058 1.971 30 Vso (Volt) 2.895 2.617 2.265 PO 0.337 0.271 0.149 d t~m] 3.4 3.8 4.0 d~n ~m] 0.29 0.33 0.34 .
-lZ8922~3 ~ixture "B"
~=300 ~=60 ~=90 a=30 ~=15 ~= O
~=90 ~=90 ~=90 S -- _ V10 (Volt) 1.562 1.614 1.441 Vso (Volt) 2.092 2.015 1.671 Po 0.339 0.248 0.159 d t~m] 4.5 6.0 7.0 dQn [~m] 0.32 0.43 0.50 10Xey to Table 2:
V10 denotes the optical threshold voltage at 10% extinc-tion (or 90% transmission).
V50 denotes the voltage at 50% extinction or transmission.
p denotes the steepness of the transmission curve at a viewing or light incidence angle ~ = 0 in accordance with the formula:
V - V
Po =
vlo ~ 'igure 3 shows the contrast curves characteristic of the electro-optical behaviour as compared with a conventional twisted nematic cell, the curves having been taken in white light at ~ = 30, ~ = 30. and ~ = 90 tcurve 1) at ~
= 60, ~ = 15 and ~ = 90 (curve II) and at ~ = 90, ~ = 0 and ~ = 90 (twisted nematic cell, curve III).
Clearly, the curve becomes steeper as the angle of twist increases.
12~9228 The cell hereinbefore described can be operated in transmission and in reflection.
~5
The invention relates to a liquid crystal display (LCD) cell comprising a twisted nematic liquid crystal layer which is disposed between two plates and polarizers having electrodes and surface orientations and which has a positive dielectric anisotropy.
The invention relates more particularly to an LCD cell of the kind set out wherein the nematic liquid crystal layer has a very low optical path difference.
If they are to have a high multiplex ratio, LCD cells must of course have a steep electro-optical characteristic.
The corresponding development was concentrated on highly twisted nematic structures. The term "highly twisted nematic structures" is to be understood as denoting structures having a twist of more than 90. Of course, doping with chiral additives is usually necessary to produce such a twist.
The advantages of liquid crystal cells having highly twisted nematic structures are a very steep electro-optical characteristic and a wide viewing angle range. The steep electro-optical characteristic leads to high multiplex ratios which are necessary to provide indications of high information density.
However, little regard was had for the fact that the main requirement for some purposes is not a high multiplex ratio but the possiblity of providing a highly differentia-ted grey scale. This is more particularly the case, for example, for television applications.
~u/10.8.87 It is therefore the object of the invention to provide an LCD cell having an electro-optical characteristic with a very low slope.
According to the invention, this object is achieved by an LCD cell of the kind hereinbefore mentioned which is characterized by the combination of: a twist angle ~ of from 10 to 80: an angle ~ between the surface orienta-tion direction and the polarization direction of the plate on the light incidence side of from -30 to 60: an angle ~ between the polarization directions of the two pola-rizers of from 80 to 110; and an optical path difference ~n.d of from 0.2 to 0.7 ~m.
In particular, the liquid crystal display (LCD) cell, according to one embodiment of the invention comprises a twisted nematic liquid crystal having a positive dielectric anisotropy which is disposed between two plates having electrodes and surface orientations.
The plates are disposed between two polarizers, and the LCD cell further includes, in combination, a twist angle 0 between the nematic directors of the liquid crystal at the respective plates of from about 10 to about 80; an angle e between the surface orientation direction and the polarization direction of the plate on the light incidence side of from about -30 to about 60; an angle between the polarization direction of the two polarizers of from about 80 to about 110: and an optical path difference ~n.d of from about 0.2 to about 0.7~m.
For the purposes of this description the following angles are to be understood as follows:
The twist angle ~ is the angle included between the planes which are defined by the two nematic directors on the 35 feont plate - i.e., the plate on the light incidence side -~ ,, ~28~2~8 2(a) and on the rear plate and which are perpendicular to theplates - i.e., in other words the angle by which the nematic directors are offset from one another. This definition corresponds to the conventional definition.
The angle ~ is the angle between the surface orienta-tion on the front plate or on the nematic director nl on the plate and the polarization direction of the polarizer associated with the last-mentioned plate. Positive values of the angle ~ indicate that the polarization direction is outside the angle ~ while negative values of ~ indicate a polarization direction between the nematic directors.
The angle ~ is the angle by which the polarizers are offset from one another. The polarizers are called crossed when they substantially bar the passage of light without any light-influencing means between them. This means that the term ~crossed~' covers all the corresponding values of and is not limited exclusively to a 9oo offset.
I'he resulting cell provides a positive contrast display and, surprisingly, is not coloured for low values of d~n and ~ = 0.
In positive contrast displays electrically energized 6egments appear dark on a bright background whereas in negative contra~t displays the situation is the converse.
Embodiments of the invention will be described herein-after with reference to the drawings wherein:
Figure 1 is a diagrammatic exploded view of an LCD cell ~5 according to the invention:
Figure 2 is a diagram showing the arrangement of angles, the 6urface orientations and the polarizers relatively to one another, and Figure 3 illustrates a voltage-contrast curve of a preferred embodiment.
The LCD cell according to the invention is of very similar construction to known cells, such as Twisted Nematic LCDs (Schadt and Helfrich, Appl. Phys. Lett. 18, 127 [1971~), so that there is no need here to go into construc-tional details. The cell according to the invention com-prises a liquid crystal layer 1 disposed between two plates 2,3 which are disposed substantially plane-parallel to one another and which are made of a transparent material such as glass or acrylic glass or plastic foils or the like. A
polarizer 4 is disposed before the front plate 2 and is preferably connected thereto, for example, by sticking. A
polarizer 5 is similar associated with the rear plate 3. The plates are separated from one another by a spacing or gap d.
~28922~3 On their surfaces facing the liguid crystal the plates 2,3 have conventional electrode coatings 6 segmented for the display of symbols or dots. Also, the surfaces are so treated as to exert a directional effect on the adjacent liquid crystal molecules and thus determine the direction of the nematic director n. The treatment resides, for example, in rubbing the surface in one direction or in the oblique evaporation of orienting layers etc; it is not necessary, but neither is it disadvantageous, to provide a tilt angle.
The result of this treatment will be called surface orienta-~ tion for the purpose hereof. An arrow 7 indicates thesurface orientation on the front plate 2. The surface orien-tation on the rear plate 3 is offset from that of the front plate and is indicated by an arrow 8.
The front plate polarizer is 80 disposed that its polarization direction includes relatively to the twist angle in the outwards direction a predetermined angle which will be described in greater detail hereinafter. The rear polarizer is so disposed that its direction of polarization Z crosses that of the first polarizer.
The liquid crystal 1 is a nematic liquid crystal which can have chiral additives.
Figure 2 illustrates the relative angular relationships of the nematic directors and the polarization directions. As previously stated, nl is the nematic director on the front plate 2 and n2 is the nematic director on the back plate ~. The angle of twist between the two nematic directors has the reference ~. This angle is approximately 50 in the present embodiment. However. it can vary on either side of 50. Satisfactory results are obtained with absolute values of ~ between 10 to 80, preferably 20 and 60, more particularly 30 and 50.
The front polarizer 4 has a polarization direction Pl.
In this embodiment such direction is offset by an angle of 20O from the nematic director nl. However, the direc-tion Pl can vary by an angle ~ from the nematic director nl in a range of from -30 < ~< 60. In other words, the polarizers can be arranged symmetrically of the nematic directors. The condition for this is ~ = (90-~)/2 if = 90. Symmetry is preferable but not obligatory. The polarization direction P2 f the rear polarizer 5 is offset from that of the front polarizer Pl by an angle ~
~ which is preferably 90. However, satisfactory results are obtained with an angle ~ of from 80 to 110. The polari-zation directions Pl and P2 can be changed over without adverse results.
~5 In other preferred embodiments, for example, ~ = 30O, ~ = 30 and ~ = 90, the following liquid crystal mixture (mixture "A") being used in a layer of a thickness d = 3.4 ~m:
Mixture "A"
ComPonent Concentration tweiaht ~) 0d(4)CP p-ttrans-4-(4-pentenyl) cyclohexyl]benzonitrile 8,000 5CP p-(trans-4-pentylcyclo-hexyl)benzonitrile11,000 4P(l)P p-(5-butyl-2-pyrimidinyl)-benzonitrile 3,000 35 sCAP02 P-t2-(trans-4-pentylcyclo-hexyl)ethyl~-ethoxybenzene 6,000 . .
:
128922~
3CEC3 trans-4-propylcyclohexane carboxylic acid-trans-4--propylcyclohexyl ester 8,000 4CEC4 trans-4-butylcyclohexane carboxylic acid-trans-4--butylcyclohexyl-ester11,000 5CEC3 trans-4-pentylcyclohexane carboxylic acid-trans-4--propylcyclohexyl-ester11,000 5CPAC4 1-t2-(trans-4-butylcyclo-hexyl)-ethyl]-4-(trans-4--pentylcyclohexyl)benzene 9,500 ~5 5CPPAC4 4-[2-(trans-4-butylcyclo-hexyl)-ethyl]4'-(trans-4--pentyl-cyclohexyl)biphenyl 5,500 20 sCPAPAC4 4-(trans-4-pentylcyclohexyl) -4'-t2-(trans-4-butylcyclo-hexyl)-ethyl]-l,l'-ethylene-diben~ene 7,000 25 4CEP02 trans-4-butylcyclohexane carboxylic acid-p-ethoxy--phenylester 11,000 5CEP01 trans-4-pentylcyclohexane carboxylic acid-p-methoxy-hexylester 9,000 A second example was prepared with the following mixture "B":
.
~ ' .
.
.
:
i289228 Mixture "B" Concentration ComPonent (weiaht %) 4Ptl)P p-(5-butyl-2-pyrimidinyl)-benzonitrile 8,8Z0 0d(3)CP p-~trans-4-(3-butenyl)-cyclohexyl]benzonitrile 7,390 L0 ld(3)CP p-~trans-4-(3E-pentenyl)-cyclohexyl]benzonitrile 7,4Zo 0dt4)CPP 4'-[trans-4-(4-pentenyl)-4-biphenylcarbonitrile 6,170 ~5 3CEC3 trans-4-propylcyclohexane carboxylic acid-trans-g-propylcyclohexyl ester 21,050 20 4CEC4 trans-4-butylcyclohexane carboxylic acid-trans-4-butylcyclohexylester 28,100 5CEC3 trans-4-pentylcyclohexane carboxylic acid-trans-4-propylcyclohexylester 21,050 The designation of the components is known to the skilled addressee. Reference is made in this connection, for example to the publication of Schadt, M. et al in Mol.
Cryst. Lig. Cryst. 122 (1985) 241ff and in Proc. Int. Displ.
Res. Conf., San Diego (1985).
The following Table 1 lists the relevant parameters of the two mixtures "A" and "B".
~289228 Table 1 Mixture "A" Mixture "B"
5 Clearing point TCl [C] 72 42.5 Melting point Tm [C] <-20 <o nO 1,432 1,476 Optical anisotropy ~n 0,086 0,072 Viscosity ~ 23 21 / (at 22C) ~m pa. s]
- The electro-optical results compiled in ~he following Table 2 were obtained with these mixtures. The results achieved with the novel cell according to the invention are in each case compared with the values obtained with the same liquid crystal mixtures in a conventional twisted nematic cell and listed in the third column.
Table 2 Mixture "A"
~=30 ~=60 ~=90 ~=30 ~=lS ~= 0 ~=so ~=so llr=90 Vlo (Volt) 2.165 2.058 1.971 30 Vso (Volt) 2.895 2.617 2.265 PO 0.337 0.271 0.149 d t~m] 3.4 3.8 4.0 d~n ~m] 0.29 0.33 0.34 .
-lZ8922~3 ~ixture "B"
~=300 ~=60 ~=90 a=30 ~=15 ~= O
~=90 ~=90 ~=90 S -- _ V10 (Volt) 1.562 1.614 1.441 Vso (Volt) 2.092 2.015 1.671 Po 0.339 0.248 0.159 d t~m] 4.5 6.0 7.0 dQn [~m] 0.32 0.43 0.50 10Xey to Table 2:
V10 denotes the optical threshold voltage at 10% extinc-tion (or 90% transmission).
V50 denotes the voltage at 50% extinction or transmission.
p denotes the steepness of the transmission curve at a viewing or light incidence angle ~ = 0 in accordance with the formula:
V - V
Po =
vlo ~ 'igure 3 shows the contrast curves characteristic of the electro-optical behaviour as compared with a conventional twisted nematic cell, the curves having been taken in white light at ~ = 30, ~ = 30. and ~ = 90 tcurve 1) at ~
= 60, ~ = 15 and ~ = 90 (curve II) and at ~ = 90, ~ = 0 and ~ = 90 (twisted nematic cell, curve III).
Clearly, the curve becomes steeper as the angle of twist increases.
12~9228 The cell hereinbefore described can be operated in transmission and in reflection.
~5
Claims (9)
1. A liquid crystal display (LCD) cell, comprising a twisted nematic liquid crystal having a positive dielectric anisotropy, which is disposed between two plates having elec-trodes and surface orientations, and wherein the plates are disposed between two polarizers, and further including, in combination, a twist angle ? between the nematic directors of the liquid crystal at the respective plates of from about 10° to about 80°; an angle .theta. between the surface orientation direction and the polarization direction of the plate on the light in-cidence side of from about -30° to about 60°; an angle ? between the polarization directions of the two polarizers of from about 80° to about 110°; and an optical path difference .DELTA.n.d of from about 0.2 to about 0.7 µm.
2. The cell according to claim 1, wherein the optical path difference .DELTA.n.d is in a range from about 0.3 to about 0.5 µm.
3. The cell according to claim 1, wherein the twist angle ?
is in a range from about 20° to about 60°.
is in a range from about 20° to about 60°.
4. The cell according to claim 1, wherein the twist angle ?
is in a range from about 30° to about 50°.
is in a range from about 30° to about 50°.
5. The cell according to claim l, wherein the angle .theta.-is defined by the condition .theta.=(90°-?)/2, the angle ? between the polarizers being 90°.
6. The cell according to claim 1, wherein the angle .theta. is in a range from about 0° to about 60°.
7. The cell according to claim 1, wherein the angle .theta. is in a range from about -30° to about 0°.
8. The cell according to claim 1, wherein the angle ? is about 90°.
9. A liquid crystal display (LCD) cell, comprising a twisted nematic liquid crystal having a positive dielectric anisotropy, which is disposed between two plates having des and surface orientations, and wherein the plates are disposed between two polarizers, and further including, in combination, a twist angle 0 between the nematic directors of the liquid crystal at the respective plates of from about 30° to about 50°; an angle e between the surface orientation direction and the polarization direction of the plate on the light incidence side of from about -30° to about 60°; an angle ?
between the polarization directions of the two polarizers of from about 80° to about 110°; and an optical path difference-.DELTA.n.d of from about 0.2 to about 0.7 µm.
between the polarization directions of the two polarizers of from about 80° to about 110°; and an optical path difference-.DELTA.n.d of from about 0.2 to about 0.7 µm.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH423486 | 1986-10-24 | ||
| CH4234/86 | 1986-10-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1289228C true CA1289228C (en) | 1991-09-17 |
Family
ID=4272310
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000548326A Expired - Fee Related CA1289228C (en) | 1986-10-24 | 1987-10-01 | Liquid crystal display device |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4896947A (en) |
| EP (1) | EP0264667B1 (en) |
| JP (1) | JPS63115137A (en) |
| KR (1) | KR940008528B1 (en) |
| CN (1) | CN87107121A (en) |
| AT (1) | ATE83081T1 (en) |
| AU (1) | AU605793B2 (en) |
| CA (1) | CA1289228C (en) |
| CS (1) | CS275803B6 (en) |
| DD (1) | DD264303A5 (en) |
| DE (1) | DE3782916D1 (en) |
| DK (1) | DK555487A (en) |
| GR (1) | GR3007399T3 (en) |
| HK (1) | HK63695A (en) |
| IL (1) | IL84202A (en) |
| NO (1) | NO874414L (en) |
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| JP2551848B2 (en) * | 1989-07-25 | 1996-11-06 | セイコープレシジョン株式会社 | Ferroelectric liquid crystal panel |
| JPH0387719A (en) * | 1989-08-30 | 1991-04-12 | Nec Corp | Liquid crystal display panel |
| NL9000686A (en) * | 1990-03-23 | 1991-10-16 | Koninkl Philips Electronics Nv | LIQUID CRYSTAL DISPLAY. |
| US5555113A (en) * | 1990-03-23 | 1996-09-10 | U.S. Philips Corporation | Liquid crystal display device with twist angle φ of 70° to 90°and alignment to polarization direction angle between φ/2+30°and φ/2+60° |
| WO1992017813A1 (en) * | 1991-04-03 | 1992-10-15 | MERCK Patent Gesellschaft mit beschränkter Haftung | Electro-optical system |
| US6327010B1 (en) * | 1992-02-03 | 2001-12-04 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Electrooptical system |
| EP0522620B1 (en) * | 1991-06-28 | 1997-09-03 | Koninklijke Philips Electronics N.V. | Display device |
| KR100231082B1 (en) * | 1991-12-09 | 1999-11-15 | 요트. 게이.아. 롤페즈 | Display device comprising liquid crystalline material |
| JP3732242B2 (en) * | 1994-02-18 | 2006-01-05 | シャープ株式会社 | Liquid crystal display |
| US5933207A (en) * | 1995-10-23 | 1999-08-03 | Hughes Electronics Corporation | Reflective-type liquid crystal displays using mixed-mode twist nematic cells |
| US5726723A (en) * | 1996-01-31 | 1998-03-10 | Technology Research International Corporation | Sub-twisted nematic liquid crystal display |
| US5936697A (en) * | 1996-06-07 | 1999-08-10 | International Business Machines Corporation | Self-compensated twisted nematic mode for reflective light valves |
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| US6166838A (en) | 1997-03-24 | 2000-12-26 | Chorum Technologies, Inc. | Optical add/drop wavelength switch |
| US5883687A (en) * | 1997-04-02 | 1999-03-16 | International Business Machines Corporation | Polarization independent liquid crystal phase gratings for reflective spatial light modulators |
| US5870164A (en) * | 1997-06-20 | 1999-02-09 | International Business Machines Corporation | Polarization dependent twisted nematic liquid crystal devices for reflective spatial light modulators |
| US6094246A (en) * | 1998-01-06 | 2000-07-25 | Chorum Technologies | Acute twist nematic liquid crystal electro-optic modulator for use in an infrared optical communication system having extinction ratio of -25db |
| JP3212946B2 (en) | 1998-06-02 | 2001-09-25 | 日本電気株式会社 | Active matrix type liquid crystal display |
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| US6396609B1 (en) | 1999-12-20 | 2002-05-28 | Chorum Technologies, Lp | Dispersion compensation for optical systems |
| US6559992B2 (en) | 2000-03-27 | 2003-05-06 | Chorum Technologies Lp | Adjustable chromatic dispersion compensation |
| KR100595298B1 (en) * | 2000-09-23 | 2006-07-03 | 엘지.필립스 엘시디 주식회사 | HTN mode liquid crystal display device |
| EP1249728A3 (en) | 2001-04-12 | 2002-11-27 | Element Displays Dr. Wiemer GmbH | Liquid crystal display device |
| US6784955B2 (en) * | 2001-10-01 | 2004-08-31 | The Hong Kong University Of Science And Technology | Optically optimized permanently bistable twisted nematic liquid crystal displays |
| US20030142257A1 (en) * | 2002-01-28 | 2003-07-31 | International Business Machines Corporation | Multi-domain low twist angle liquid crystal cells and methods of production thereof |
| US7236219B2 (en) * | 2003-11-28 | 2007-06-26 | The Hong Kong University Of Science And Technology | Color twisted nematic liquid crystal displays |
| WO2005080387A2 (en) * | 2004-02-20 | 2005-09-01 | Synthon B.V. | Processes for making pioglitazone and compounds of the processes |
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| US7637622B2 (en) * | 2005-10-11 | 2009-12-29 | 3M Innovative Properties Company | Control of an automatic darkening filter |
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| US8194063B2 (en) * | 2009-03-04 | 2012-06-05 | Global Oled Technology Llc | Electroluminescent display compensated drive signal |
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-
1987
- 1987-09-29 EP EP87114162A patent/EP0264667B1/en not_active Expired - Lifetime
- 1987-09-29 AT AT87114162T patent/ATE83081T1/en not_active IP Right Cessation
- 1987-09-29 DE DE8787114162T patent/DE3782916D1/en not_active Expired - Lifetime
- 1987-10-01 CA CA000548326A patent/CA1289228C/en not_active Expired - Fee Related
- 1987-10-02 CS CS877126A patent/CS275803B6/en unknown
- 1987-10-19 IL IL84202A patent/IL84202A/en not_active IP Right Cessation
- 1987-10-19 AU AU79880/87A patent/AU605793B2/en not_active Ceased
- 1987-10-20 KR KR1019870011627A patent/KR940008528B1/en not_active IP Right Cessation
- 1987-10-22 NO NO874414A patent/NO874414L/en unknown
- 1987-10-22 DD DD87308192A patent/DD264303A5/en not_active IP Right Cessation
- 1987-10-23 JP JP62268023A patent/JPS63115137A/en active Pending
- 1987-10-23 DK DK555487A patent/DK555487A/en not_active Application Discontinuation
- 1987-10-23 CN CN198787107121A patent/CN87107121A/en active Pending
-
1989
- 1989-06-14 US US07/366,332 patent/US4896947A/en not_active Expired - Lifetime
-
1993
- 1993-03-18 GR GR930400450T patent/GR3007399T3/el unknown
-
1995
- 1995-04-27 HK HK63695A patent/HK63695A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0264667B1 (en) | 1992-12-02 |
| NO874414D0 (en) | 1987-10-22 |
| EP0264667A1 (en) | 1988-04-27 |
| CS275803B6 (en) | 1992-03-18 |
| HK63695A (en) | 1995-05-05 |
| GR3007399T3 (en) | 1993-07-30 |
| IL84202A0 (en) | 1988-03-31 |
| DD264303A5 (en) | 1989-01-25 |
| AU7988087A (en) | 1988-04-28 |
| KR880005479A (en) | 1988-06-29 |
| DE3782916D1 (en) | 1993-01-14 |
| IL84202A (en) | 1991-06-30 |
| US4896947A (en) | 1990-01-30 |
| NO874414L (en) | 1988-04-25 |
| ATE83081T1 (en) | 1992-12-15 |
| JPS63115137A (en) | 1988-05-19 |
| DK555487D0 (en) | 1987-10-23 |
| CN87107121A (en) | 1988-05-11 |
| AU605793B2 (en) | 1991-01-24 |
| KR940008528B1 (en) | 1994-09-22 |
| DK555487A (en) | 1988-04-25 |
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