CA1170407A

CA1170407A - Expanded metal containing wires and filaments and methods of producing the same

Info

Publication number: CA1170407A
Application number: CA000395258A
Authority: CA
Inventors: William K. Mcdonald
Original assignee: Teledyne Industries Inc
Current assignee: TDY Industries LLC
Priority date: 1981-01-30
Filing date: 1982-01-29
Publication date: 1984-07-10
Also published as: SE8200383L; AT388317B; FR2499299B1; BE891934A; CH645043A5; DE3203222C2; FR2499299A1; US4414428A; IT1149526B; IT8219383A0; JPH0444365B2; GB2092043B; ATA34182A; DE3203222A1; JPS57147807A; SE455427B; BR8200492A; GB2092043A

Abstract

ABSTRACT OF THE DISCLOSURE

A wire filament or multifilament wire or cable having an expanded metal or foraminous metal concentrically or semiconcentrically layered along the length of the wire so that the spaces or holes in the metal open radially of the wire or filament. The expanded or foraminous metal can be used in said wires or filaments as a strengthening layer, a conducting layer, or a diffusion barrier layer.

Description

~ ~7~D41;~7 1, EXPANDED METAL CONTAINING WIRES AND FILAMENTS AND
METHODS OF PRODUCING THE S~ME
The present invention relates to production of wires containing e~panded or foraminous metal as either a reinforcing element or barrier layer. By expanded metal is meant metal that has been expanded to produce a foraminous or network structure therein.
In the past, composites for the production of rods, cables, or wires were produced by laminating the metals or combining them in some way and subsequently fabricating them to final dimensions.
As an example, methods of producing niobium tin-wire having fine continuous filaments have been costly and unreliable because niobium rods are used for forming the conductor filaments. The components for construction have dimensions of 1/8" diameter or larger, thus requiring a great reduction to produce a wire with one micron diameter filaments. The wires are usually produced by placing the niobium rods in a bronze billet and extruding the billet several times to reach a certain size filament of the niobium rod. This wire produced is rebundled with other wires and again extruded. In the diffusion process whereby the tin in the bronze is diffused into the niobium, large Kirkendall voids are produced in the bronze when the niobium filaments are of large dimensions, over 10 microns. Large Rirkendall voids are detrimental to the wire.
Further, because these wires produced by the prior art processes are composed of individual and separate filaments, these filaments tend to break during the fabrication process because of being extruded from such a large diameter to such a small diameter. When individual filaments break, they cause a weakening of the bulk wire and eventually can cause the wire to break, thus decreasing the yield of usable product.
In other instances the barrier layers are provided to prevent diffusion of reactive metals from one area, such as bronze-tin, into an area such as copper.
In this case the billet is formed by circumferentially :. . ~ ' ' ' ' ' 4~7 laminatin~ a barrier layer onto the center rod of the billet between the layers to be protected from one another.
In normal present day processes, it is necessary to fabricate the wire billets through extrusion processes and to re-extrude several times to reach final dimensions where the wire is drawn through dies. Each of these extrusions is very hard on the filaments and is also very expensive to perform. It is, therefore, desirable that there be found another method of producing composites capable of being fabricated to form wires having fine niobium alloy filaments which are free of the detriments of past processes, i.e., expense and filament breakage.
In accordance with the present invention, it has been found that metal composites of greater strength and better conductivity can be produced by having one layer of the composite in expanded or foraminous form.
Specifically, wires or filaments or multifilament wires are produced containing expanded or foraminous metal as a diffusion barrier, strengthening or superconducting layer, either concentric or semiconcentric, along the length of the wire.
This invention achieves the production of wires, filaments, or cables, rods and wires containing multifilaments which in themselves contain at least one concentric or semiconcentric layer of pure or laminated expanded or foraminous metal. This expanded or foraminous layer can be either laminated with another metal layer or it can be in its pure form having no other layers therewith. By semiconcentric is meant that where there are at least two component metals in the wire or filament, the expanded or foraminous layer can be in longitudinal strips along the length of the wire but not completely surrounding the wire.
This expanded metal layer can function in three categories. It can function as a strengthening layer, as a diffusion barrier between two layers that might react, and as a superconducting layer itself. When acting as a .. .

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~3L7~7 strengthening layer, it can be both in pure form and composite form, i.e., laminated ~o another metal prior to being used in the wire formation. In this form, it can be made from Nb, Nb alloys (NbTi), Ta, Ta alloys, Ni, Ni alloys, V, and V alloys. In this function it can be a layer completely surrounding an inner layer of the wire material to be extruded, it can be between two layers, or it can be in strips not touching each other. However, it is always along the length of the wire or billet so that the spaces or holes in the expanded metal open radially of the wire or filament.
When the expanded metal is used as a superconductin~ filament, it can be made of all of the same metals as used when it functions as a strengthening material except for those materials which are not superconductors. It is also used in the structure in all of the above possible configurations set forth for strengthening materials. Its use in this regard as a superconductor is determined by the surrounding metals used in the formation of the wire or filament.
When the expanded metal material is used as a diffusion barrier, it is made from Nb, Ta, V, Ni, alloys of these metals either separately or in combination.
Here again its function as a diffusion barrier will ~5 depend on the other metals used in the formation of the wire or billet or filament. There should be at least two other metals when used for this purpose.
The expanded metal when laminated with another metal can be wound upon itself in a jellyroll fashion to form a billet which is subsequently extruded to form wires and billets which can be combined to form multifilament conductors. It is also possible that the expanded metal, either in the above-referenced laminated form or in its pure form, can be wound around a core material which is usually in the formation of a rod.
This core material can have several functions, said functions determining its composition. When this core material is acting as a stabilizer, it can be formed from copper or aluminum. When it is being used for 1~7'~

incorporating reactant elements, it can be made from tin, gallium, germanium, aluminum and silicon or combinations of these. It can be a]so made from copper, tin, bronze, copper-gallium-bronze, or tin-copper alloys having a small percentage of copper, i.e., 13% copper. When being used as a strengthening material, the core can be made of brass, bronze, reinforced copper, i.e., NbCu, Ni, Ni alloys, i.e., CuNi, and Al alloys. IIere again the function of the core depends on the particular composite wire being formed. It is not necessary to always have a core material, but in certain instances it is efficacious for one or more of the above reasons.
In the making of these wires or filaments there is often used a ductile matrix material. This material lS can be made of the same material as the core material and can be used in the core of a wire. It can also be used as the material to which the expanded metal is laminated prior to wrapping around a core or being jellyrolled upon itself for purposes of producing the billet from which the wire or filaments are extruded. This material can also be used in the outside cladding or casing of the billet. As its name signifies, the material lends ductility to the billet which aids in the extrusion thereof.
In the making of a billet there is often used a surrounding or claddiny material to aid in the drawing of the billet into wire or filaments. This material can be copper, nickel, aluminum, or bronze containing reactant materials such as tin, gallium, germanium, aluminum, `30 silicon and combinations of these.
Specifically, in the present invention it has been found that many of the problems of the past methods of producing composites~ particularly superconductor wires having fine filaments, can be solved by using expanded metal as opposed to metal rods. This expanded metal has many advantages of prior processes. It allows a greatly increased versatility and composite design, much finer filaments with less reduction required, a uniform conductor cross-section while still having the advantages of a single fine filamenk. These advantages are attributed to the use of a finer starting material, therefore requiring less reduction to achieve even finer filaments than prior methods. secause the starting size of the conductor is fine, final dimensions o-f the superconductor can be sufficiently fine to allow for short reaction times, thereby reducing Kirkendall void formation and utiliziny the ductile charcteristics of extremely fine filaments of brittle metal compounds.
By means of the present process, one can produce a long length conductor with fine conductor filaments at a much lower cost than present processes.
This is because the starting material is of very fine dimensions requiring less reduction. Because of the lS decreased threat of breakage, it is possible by the present method to produce long unbroken lengths which are extremely difficult to achieve using present-day methods.
The invention is described further, by way of illustration, with reference to the accompanying drawings, in which:
Figure 1 discloses a cross-sectional view of a lamina consisting of a solid metal layer and an expanded metal layer;
Figure 2 discloses a top view of Figure 1 25 showing the expanded metal layer overlaying a solid metal layer;
Figure 3 discloses a cross-sectional of a billet rolled from the lamina of Figure 1 around a copper rod and clad in copper; and Figures 4, 5, 6, 7, 8 and 9 disclose various cross-sections of wires, filaments, or billets produced by the process of this invention.
Referring first to Figures 1 to 3 of the drawings, in accordance with the present invention of 35 ma~ing wires, one method is by taking a lamina as shown in Figures 1 and 2, wherein a bronze layer (1) is layered with a layer of expanded niobium metal (2). The bronze layer is used to supply tin to the niobium. It has been found that the tin can be diffused into the niobium in ~3~7~ 7 this way, and, therefore, the bronze layer is needed so as to diffuse the tin into the niobium and produce Nb3Sn.
This method has the desirable reaction kinetics for the solid state diffusion reaction since it is more difficult for the tin to be placed on the niobium and achieve the same. The bron~e is of standard specifications and contains anywhere from 10 to 14~ tin. This lamina is then rolled like a jellyroll around a copper core rod as shown in Figure 3 and marked 3. The bronze-niobium layer (4) is wound around the copper rod (3) and subsequently clad with an outer layer of copper (5), ~orming a billet having the cross-sectional shown in Figure 3.
The copper cladding is helpful to facilitate fabrication, making it easy to draw the wire. It further provides cryogenic stability having high thermal conductivity. The wire then can be reduced and drawn into any cross-sectional shape, i.e., round, square, elliptical, or flat.
It is also possible to produce a billet for extrusion into a wire or filament wherein no core material is used, the lamina of Figure 1 being jellyrolled upon itself, having a cross-section as shown in Figure 4.
Figures 5 through 9 illustrate various cross-sections of billets, wires, or filaments which have been fabricated for various functions and reasons.
Figure 5 is illustrative of the use of a non-laminated pure expanded metal (6) wrapped around a core (3) similar to that shown in Figure 3 and cladded with a cladding material (5). This cross-section depicts the use of the expanded metal as a strengthening material only. This is sometimes used to produce strong filaments which may be used in conjunction with conducting filaments. This is because the conducting filaments are 35 not as strong due to the reactant materials contained therein. In that case, when a multifilament wire, cable or rod is formed some of the filaments are merely strengthening filaments having a cross-section like ~7~ 7 Eigure 5 to lend strength to the conductiny filaments such as those shown in Eigures 3, 4, 6, 7, 8, and 9.
Figure 6 illustrates the use of pure expanded metal (6) as a diffusion barrier. In this cross-section of the wire or bille~ there is shown a core material (3) and a reactant containing material (4) formed in the same way as that of Figure 3. The diffusion barrier ~6) prevents the reactant material in layer (4) from reacting with the cladding material (5) which would decrease the ability of the cladding layer to be a stabilizing conductor. Instead, the reactant material will react with the diffusion barrier material which is a much slower reaction.
Figure 7 is a similar cross-section to Figure 6. However, there is contained therein strips of barrier material, such as phosphor-bronze (7), which prevent the reaction of the reactants with the diffusion barrier in certain areas so as to decrease this reaction. This is sometimes desirable when the conductive material is being protected in that the diffusion of the reactant material into the expanded metal can cause the expanded metal to become a conducting ring around the superconducting material inside. When this happens it sometimes causes a condition known as flux jumping which can set up resistance losses, producing an unstable condition in the conductor. This usually occurs morè readily where alternating current is used as opposed to direct current.
Figure 8 is a cross-section of a billet or wire wherein two diffusion barriers are used when it is desired to protect not only the cladding material from the conducting material (4), but also to protect the core material from the same conducting material (4), Figure 9 shows the cross-section of a billet wherein the foraminous metal is cut into strips and incorporated in a jellyroll configuration contained in a ductile matrix material.
The invention is illustrated further by the following Examples.
Example I

~7~ 7 A billet was constructed with the dimensions

2.375 inch (6.03 cm) outside diameter by 6 inches (15.2 cm) long and having a composite of expanded niobium on bronze wrapped around a copper rod and clad with a copper casingO The billet contained approximately 8~ Nb by cross-section and was fabricated to 0.020 inch (0.05 cm) diameter continuous wire by conventional methods and reacted by conventional me-thods (annealing at 600C).
The critical temperature, i.e., the temperature at which the wire exhibited zero resistance to current - flcw and hence the temperature at which the wire became superconducting, was determined and compared with the known critical temperature for pure niobium. In addition, the wire was subjected to heat treatment at 800C for 15 minutes and the critical temperature again determined. The results are reproduced in the following Table I:
TABLE I
Sample Critical Tem~erature Pure niobium 9K
Wire (no heat treatment) 11K
Wire (with heat treatment) 17.6K
The results of the above Table I show that an improved (i.e., higher) critical temperature is attained with respect to pure niobium without heat treatment and much improved critical temperature is attained by a final heat treatment to effect diffusion of tin into the niobium from the bronze to promote alloy formation.
Examples M to M10 A series of bronze billets was made having certain compositions and sizes and fabricated into wires.
These billets are set forth in Table II below where the remarks column indicates certain observations on fabrication. It can be seen from Table II that the billets correspond to various Figure cross sections in the drawings.

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4~7 Examples R3 to R12 Some ~urther billets were made and tested for strength. These billets were fabricated according to the processes of the present invention and had the dimensions s and compositions set forth in Table III below. They were then tested for strength and the results are set forth in Table IV below.

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., :
."

Claims

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:

1. An extruded wire or filament containing at least one metal layer which is formed from a foraminous metal prior to extrusion.

2. The wire of Claim 1 wherein the foraminous metal is an expanded metal.

3. The wire of Claim 1 wherein there are at least two metals, one of which is a foraminous metal.

4. The wire of Claim 3 wherein the foraminous metal acts as a conductor and there are reactant elements in the other metal.

5. The wire of Claim 1 wherein there are at least three metals and the foraminous metal acts as a diffusion barrier.

6. The wire of Claim 3 wherein the expanded metal is used as a strengthening material and is selected from the group consisting of Nb, Ta, Ni, V, and alloys thereof.

7. The wire of Claim 3 wherein the foraminous metal acts as a conductor and is selected from the group consisting of Nb, Ta, V, and alloys thereof.

8. The wire of Claim 5 wherein the foraminous metal acts as a diffusion barrier and is selected from the group consisting of Nb, Ta, V, Ni, and alloys thereof.

9. The wire of Claim 5 wherein there is contained longitudinal strips of a barrier layer between the diffusion barrier and a reactant layer.

10. The wire of Claim 1 wherein the foraminous metal is wrapped around a core metal.

11. The wire of Claim 10 wherein the core acts as a stabilizer and is selected from the group consisting of Cu and Al.

12. The wire of Claim 10 wherein the core containing at least one reactive element selected from the group consisting of Sn, Ga, Ge, Al, Si, CuSn, CuGa, SnCu, and combinations of these.

13. The wire of Claim 10 wherein the core acts as a strengthening material and is formed from a metal selected from the group consisting of brass, bronze, reinforced copper, Ni alloys and Al alloys.

14. The wire of Claim 1 wherein the foraminous metal is contained in or laminated to a ductile matrix material.

15. The ductile matrix material set forth in Claim 14 being a metal selected from the group consisting of Cu, Al, bronze, tin, nickel, and brass.

16. The wire of Claim 1 being contained in a cladding material.

17. The cladding material of Claim 16 being formed from a metal selected from the group consisting of Cu, Ni, Al and bronze.

18. The bronze of Claim 17 containing reactant materials selected from the group consisting of Sn, Ga, Ge, Al and Si.

19. The method of producing a wire or filament containing at least one foraminous metal layer comprising wrapping the foraminous metal layer around a rod of at least one metal to form a billet and subsequently elongating the billet.

20. The method of Claim 19 wherein the rod is formed of several layers.

21. The method of Claim 20 wherein one of the layers is a foraminous metal layer.

22. The method of Claims 19 or 20 wherein the billet is drawn to form a wire then combined with other wires formed by the same method and subsequently redrawn to form a wire.

23. The method of Claims 19 or 20 wherein the outer foraminous metal layer is covered with a cladding layer of metal prior to elongation.

24. The method of Claims 19 or 20 wherein the foraminous metal layer is discontinuous.